23418-91-9

Basic information

• Product Name: 9-Borabicyclo[3.3.1]nonane,9-phenyl-
• Synonyms: 9-Borabicyclo[3.3.1]nonane,9-phenyl-
• CAS NO: 23418-91-9
• Molecular Formula: C₁₄H₁₉B
• Molecular Weight: 198.11
• Mol File: 23418-91-9.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 286.5°Cat760mmHg
• Flash Point: 127.1°C
• Appearance: /
• Density: 0.95g/cm³
• Vapor Pressure: 0.00454mmHg at 25°C
• Refractive Index: 1.521
• CAS DataBase Reference: 9-Borabicyclo[3.3.1]nonane,9-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 9-Borabicyclo[3.3.1]nonane,9-phenyl-(23418-91-9)
• EPA Substance Registry System: 9-Borabicyclo[3.3.1]nonane,9-phenyl-(23418-91-9)

Safety Data

• Hazardous Substances Data: 23418-91-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H19B/c1-2-6-12(7-3-1)15-13-8-4-9-14(15)11-5-10-13/h1-3,6-7,13-14H,4-5,8-11H2

Upstream product

• 75-75-2 methanesulfonic acid 
• 591-51-5 phenyllithium 
• 280-64-8 9-bora-bicyclo[3.3.1]nonane 
• 280-64-8 9-borabicyclo[3.3.1]nonane 
• 22086-34-6 9-chloro-9-bora-bicyclo[3.3.1]nonane 
• 38050-71-4 9-methoxy-9-borabicyclo[3.3.1]nonane 
• 108-86-1 bromobenzene 
• 38050-71-4 9-methoxy-9-BBN 
• 7681-65-4 copper(l) iodide 
• 100-59-4 phenylmagnesium chloride 
• 285557-42-8 9-triisopropylsilanylsulfanyl-9-bora-bicyclo[3.3.1]nonane 

Downstream Products

• 1517-63-1 4-methylphenyl(phenyl)methanol 
• 1083-56-3 1,4-diphenylbutane 
• 17734-38-2 ethyl 5-phenylpentanoate 
• 10031-93-3 ethyl 4-phenylbutyrate 
• 64806-63-9 3-phenoxypropylbenzene 
• 5073-13-2 2-(3-phenylpropyl)furan 
• 1173371-93-1 1-[1-(3-phenylpropyl)-1H-pyrrol-2-yl]ethan-1-one 
• 110045-73-3 9-(3-phenylpropyl)-9H-carbazole 
• 14310-24-8 1-bromo-4-(2-phenylethyl)benzene 
• 56644-06-5 6-phenyl-1-hexylchloride 
• 2189-60-8 Octylbenzene 
• 5663-30-9 2-(2-phenylethyl)-1,3-dioxane 
• 251107-37-6 1-t-butyloxycarbonyl-4-benzylpiperidine 
• 4410-78-0 (cyclopentylmethyl)benzene 

Relevant articles and documents

DYNAMIC NMR SPECTROSCOPY OF THE TETRAVALENT ORGANOBORATE COMPOUNDS. SYNTHESIS AND SOME UNIQUE FEATURES OF ORGANOBORATES CONTAINING THE C6H4CH2NMe2-2 LIGAND

Novel borates (ArBMe3)Li*OEt2 (I), (ArBEt)Li*OEt2 (II) and (BArPh-9-BBn)Li*OEt2 (III) (Ar=C6H4NMe2-2, 9-BBN=9-borabicyclononyl) were synthesized in the reactions of ArLi with BMe3, BEt3 and BPh-9-BBN, respectively.Detailed studies were made of 1H,

Palladium-catalyzed 1,3-diol fragmentation: Synthesis of ω-dienyl aldehydes

2-(1′-Hydroxy-2′-propenyl)cycloalkan-1-ols 1 undergo dehydrative C1-C2 bond cleavage and provide ω-dienyl aldehydes 2 under the catalysis of Pd(0) and 9-phenyl-9-BBN. The Royal Society of Chemistry.

New Method for the Synthesis of Organoboranes

Mixed organoboranes can be conveniently prepared in a single stage by treatment of a dialkylborane with various lithium dialkyl- or diaryl-cuprates.

Suzuki-miyaura cross-coupling reactions of unactivated alkyl halides catalyzed by a nickel pincer complex

A nickel(II) pincer complex, [(MeN2N)Ni-Cl], was used to catalyze alkyl-alkyl and alkyl-aryl Suzuki-Miyaura coupling reactions of unactivated alkyl halides. The coupling of 9-alkyl-9-borabicyclo[3.3.1]nonane and 9-phenyl-9-borabicyclo[3.3.1]nonane reagents with alkyl halides was achieved in modest to good yields. The reactions tolerated a variety of useful functional groups including ester, ether, furan, thioether, acetal, and Boc groups. Georg Thieme Verlag Stuttgart, New York.