23595-00-8Relevant articles and documents
Rhodium-catalyzed direct C-H amination of benzamides with aryl azides: A synthetic route to diarylamines
Ryu, Jaeyune,Shin, Kwangmin,Park, Sae Hume,Kim, Ji Young,Chang, Sukbok
, p. 9904 - 9908 (2012/10/29)
No muss, no fuss: A rhodium-catalyzed direct intermolecular C-H amination of benzamides and ketoximes using aryl azides as the amine source has been developed. The reaction exhibits a broad substrate scope with excellent functional-group tolerance, requires no external oxidants, releases N 2 as the only by-product, and produces diarylamines in high yields. Copyright