2371-70-2

Upstream product

• 917-54-4 methyllithium 
• 35739-70-9 dimethyldichlorotitanium(IV) 

Downstream Products

• 628-99-9 (R)-2-nonanol 
• 70419-06-6 (S)-nonan-2-ol 
• 1084-78-2 (1RS,2SR)-(+/-)-1,2-diphenyl-1,2-propandiol 
• 15914-84-8 (S)-1-(1-Naphthyl)ethanol 
• 42177-25-3 (R)-1-(naphth-1-yl)ethanol 
• 4217-65-6 (R,S)-2,3-diphenylbutane-2,3-diol 
• 22985-90-6 (2R,3R)-2,3-Diphenyl-butane-2,3-diol 
• 3205-25-2 (S)-1-(2-nitrophenyl)ethanol 
• 3205-25-2 (R)-(-)-1-(2-nitrophenyl)-1-ethanol 
• 7440-32-6 titanium 
• 7287-82-3 (S)-1-(2-Methylphenyl)ethanol 
• 42070-90-6 (R)-1-(2-methylphenyl)ethanol 
• 1445-91-6 (S)-1-phenylethanol 
• 1517-69-7 (R)-1-phenylethanol 

Relevant academic research and scientific papers

Titanium methyl tamed on silica: Synthesis of a well-defined pre-catalyst for hydrogenolysis of: N-alkane

Alkylation of Ti(CH3)2Cl21 by MeLi gives the homoleptic Ti(CH3)42 for the first time in the absence of any coordinating solvent. The reaction of 2 with silica pretreated at 700 °C (SiO2-700) gives two inequivalent silica-supported Ti-methyl species 3. Complex 3 was characterized by IR, microanalysis (ICP-OES, CHNS, and gas quantification), and advanced solid-state NMR spectroscopy (1H, 13C, DQ, TQ, and HETCOR). The catalytic activity of the pre-catalyst 3 is investigated in low-temperature hydrogenolysis of propane and n-butane with TONs of 419 and 578, respectively. This journal is