23837-11-8

Basic information

• Product Name: Benzene, 1-[bis[(4-chlorophenyl)thio]methyl]-4-methoxy-
• CAS NO: 23837-11-8
• Molecular Formula: C20H16Cl2OS2
• Molecular Weight: 407.384
• Mol File: 23837-11-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[bis[(4-chlorophenyl)thio]methyl]-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[bis[(4-chlorophenyl)thio]methyl]-4-methoxy-(23837-11-8)
• EPA Substance Registry System: Benzene, 1-[bis[(4-chlorophenyl)thio]methyl]-4-methoxy-(23837-11-8)

Safety Data

• Hazardous Substances Data: 23837-11-8(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 100-53-8 phenylmethanethiol 
• 106-54-7 p-Chlorothiophenol 
• 40891-01-8 4-(dimorpholinomethyl)-1-methoxybenzene 
• 4630-06-2 6-methylhept-5-en-2-ol 

Downstream Products

• 1146-44-7 4,4'-dichlorophenyl thiosulfonate 

Relevant articles and documents

Diastereoselective synthesis of tetrahydropyrans via Prins-Ritter and Prins-arylthiolation cyclization reactions

An efficient method has been developed for the synthesis of two new classes of tetrahydropyran derivatives comprising amide, tetrazole or benzothiazole moieties via a three-component reaction of 6-methylhept-5-en-2-ol, arylaldehydes and nitriles/thiols in the presence of a tetrafluoroboric acid diethyl ether complex. The reaction proceeds via the formation of an oxocarbenium ion. This protocol is highly diastereoselective and only single diastereomer has been isolated in each case.