2392-65-6Relevant articles and documents
Dakin-west reaction of n-thioacylprolines using trifluoroacetic anhydride: Novel access to 5-trifluoromethylthiazoles
Hagimoto, Yuri,Saijo, Ryosuke,Kawase, Masami
, p. 709 - 724 (2014)
The reaction between N-thioacylprolines and trifluoroacetic anhydride in the presence of pyridine afforded a good yield of 5-trifluoromethylthiazoles. This reaction proceeded through mesoionic 1,3-thiazolium-5-olates, followed by cleavage of the pyrrolidine ring and the formation of thiazoles, introducing a trifluoromethyl group at position 5 in the thiazole ring.
The circular dichroism of N-thiobenzoyl-L-alpha-amino-acids. Part VI. Assessment of the resolution of amino-acids as their N-thiobenzoyl derivatives.
Barrett,Cousins
, p. 2313 - 2315 (2007/10/05)
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