24017-91-2

Basic information

• Product Name: methyl 2'-acetyl[1,1'-biphenyl]-2-carboxylate
• Synonyms: methyl 2'-acetyl[1,1'-biphenyl]-2-carboxylate
• CAS NO: 24017-91-2
• Molecular Formula: C₁₆H₁₄O₃
• Molecular Weight: 254.28056
• Mol File: 24017-91-2.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: methyl 2'-acetyl[1,1'-biphenyl]-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2'-acetyl[1,1'-biphenyl]-2-carboxylate(24017-91-2)
• EPA Substance Registry System: methyl 2'-acetyl[1,1'-biphenyl]-2-carboxylate(24017-91-2)

Safety Data

• Hazardous Substances Data: 24017-91-2(Hazardous Substances Data)

Upstream product

• 506-82-1 dimethylcadmium 
• 67913-92-2 2,2'-biphenyldicarboxylic acid monomethyl ester chloride 
• 610-94-6 2-bromobenzoic acid methyl ester 
• 308103-40-4 (2-acetylphenyl)boronic acid 
• 610-97-9 o-iodo-methyl-benzoic acid 
• 98-86-2 acetophenone 
• 10341-75-0 (E)-1-phenylethanone oxime 
• 67-56-1 methanol 
• 186581-53-3 diazomethane 
• 24017-92-3 2'-acetyl-[1,1'-biphenyl]-2-carboxylic acid 
• 33757-48-1 N-quinolin-8-yl-benzamide 
• 325141-75-1 1-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)ethan-1-one 

Downstream Products

• 1015-89-0 6(5H)-phenanthridinone 
• 32708-39-7 7-Amino-5-oxo-5H-dibenzocyclohepten 
• 32708-47-7 dibenzo[a,c]cycloheptene-5,6,7-trione-6-phenylhydrazone 
• 32708-26-2 6-Benzoyl-7-hydroxy-5H-dibenzo[a,c]cycloheptatrien-5-one 
• 32807-95-7 7-chloro-dibenzo[a,c]cyclohepten-5-one 
• 32708-25-1 6-benzoyl-7-morpholin-4-yl-dibenzo[a,c]cyclohepten-5-one 
• 24017-92-3 2'-acetyl-[1,1'-biphenyl]-2-carboxylic acid 

Relevant articles and documents

Cobalt-Catalyzed Aerobic Oxidative C-H/C-H Cross-Coupling of Unactivated Arenes for the Synthesis of Biaryls

A mild and efficient protocol for the synthesis of 2,2′-difunctional biaryls from readily available benzamides and oximes by Co(OAc)2·4H2O catalysis has been developed. The catalytic cycle that includes aerobic oxidation of Co(I) to Co(III) is successfully achieved for the first time through dual-chelation-assisted C-H/C-H coupling with the assistance of catalytic Mn(acac)3. The catalytic system exhibits powerful reactivity and tolerates a large number of sensitive functional groups.

IRIDIUM COMPLEX COMPOUND, COMPOSITION CONTAINING THE COMPOUND AND SOLVENT, AND ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE AND ILLUMINATION DEVICE CONTAINING THE COMPOUND

PROBLEM TO BE SOLVED: To provide an iridium complex compound in which the light-emission wavelength of light emitting material is made longer. SOLUTION: The present invention provides an iridium complex compound represented by the formula (1) [Ir is an ir

Copper-Catalyzed Formation of α-Alkoxycycloalkenones from N-Tosylhydrazones

The combination of 20 mol % of copper iodide and lithium tert-butoxide triggers the formation of a broad range of substituted, functionalized α-alkoxy 2H-naphthalenones from readily available N-tosylhydrazones. The data suggests that this transformation occurs through cycloaddition of a copper carbenoid with an ester, followed by a Lewis acid-catalyzed [1,2] alkyl shift of the in situ generated alkoxyepoxide intermediate. The combination of 20 mol % of copper iodide and lithium tert-butoxide triggers the formation of a broad range of substituted, functionalized α-alkoxy 2H-naphthalenones from readily available N-tosylhydrazones. The reaction proceeds by the cycloaddition of a copper carbenoid with an ester, and a subsequent Lewis acid-catalyzed [1,2] alkyl shift of the in situ generated alkoxyepoxide intermediate.