24017-92-3

Upstream product

• 5807-65-8 diethyl biphenyl 2,2'-dicarboxylate 
• 141-78-6 ethyl acetate 
• 32708-35-3 7-oxo-5--5,7-dihydrodibenzoxepin 
• 24017-91-2 2'-acetyl-[1,1'-biphenyl]-2-carboxylic acid methyl ester 
• 67913-92-2 2,2'-biphenyldicarboxylic acid monomethyl ester chloride 
• 105-53-3 diethyl malonate 
• 7664-93-9 sulfuric acid 
• 638169-41-2 2′-acetylbiphenyl-2-carboxylic acid ethyl ester 
• 88-67-5 2-Iodobenzoic acid 
• 609-67-6 2-Iodobenzoyl chloride 
• 1829-28-3 ethyl 2-iodobenzoate 
• 6091-64-1 2-bromobenzoic acid ethyl ester 
• 308103-40-4 (2-acetylphenyl)boronic acid 
• 7535-15-1 2,2'-biphenyldicarboxylic acid dichloride 

Downstream Products

• 24017-91-2 2'-acetyl-[1,1'-biphenyl]-2-carboxylic acid methyl ester 
• 32708-25-1 6-benzoyl-7-morpholin-4-yl-dibenzo[a,c]cyclohepten-5-one 
• 32807-95-7 7-chloro-dibenzo[a,c]cyclohepten-5-one 
• 32708-26-2 6-Benzoyl-7-hydroxy-5H-dibenzo[a,c]cycloheptatrien-5-one 
• 32708-47-7 dibenzo[a,c]cycloheptene-5,6,7-trione-6-phenylhydrazone 
• 32708-39-7 7-Amino-5-oxo-5H-dibenzocyclohepten 
• 54838-55-0 6-(4-Hydroxybenzyliden)-5H-dibenzocyclohepten-5,7-dion 
• 54838-57-2 6-(3-Methoxybenzyliden)-5H-dibenzocyclohepten-5,7-dion 
• 54838-58-3 6-(4-Methoxybenzyliden)-5H-dibenzocyclohepten-5,7-dion 
• 54838-54-9 6-(2-Hydroxybenzyliden)-5H-dibenzocyclohepten-5,7-dion 
• 54838-27-6 C₃₈H₂₆O₄ 
• 54838-26-5 C₃₇H₂₃ClO₄ 
• 54838-25-4 C₃₇H₂₄O₄ 
• 54838-22-1 6-Benzyliden-5H-dibenzocyclohepten-5.7-dion 

Relevant academic research and scientific papers

IRIDIUM COMPLEX COMPOUND, COMPOSITION CONTAINING THE COMPOUND AND SOLVENT, AND ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE AND ILLUMINATION DEVICE CONTAINING THE COMPOUND

PROBLEM TO BE SOLVED: To provide an iridium complex compound in which the light-emission wavelength of light emitting material is made longer. SOLUTION: The present invention provides an iridium complex compound represented by the formula (1) [Ir is an ir

Enantioselective route to 5-methyl-And 5,7-dimethyl-6,7-dihydro-sh- dibenz[c,e]azepine: Secondary amines with switchable axial chirality

(-) -5-Methyl-6, 7-dihydro-5H-dibenz[c, e]azepine 4, a new secondary amine featuring an axis-center stereochemical relay, was prepared enantioselectively from 2'-acetylbiphenyl-2-carboxylic acid, using (R) -2-phenylglycinol as an auxiliary for the control

Novel Extension of Meyers' Methodology: Stereoselective Construction of Axially Chiral 7,5-Fused Bicyclic Lactams

A novel extension of Meyer's lactamization is reported for the preparation of seven-membered ring lactams 1a-d incorporating a biaryl unit. The required keto-esters 2a-c were readily accessible via the Suzuki coupling reaction. A borylation-Suzuki couplin

Dioxygen Transfer from 4a-Hydroperoxyflavin Anion. 2. Oxygen Transfer to the 10 Position of 9-Hydroxyphenanthrene Anions and to 3,5-Di-tert-butylcatechol Anion

The reaction of the peroxy anion of N5-ethyl-4a-hydroperoxy-3-methyllumiflavin (4a-FlEtO2-) with the anions of 3,5-di-tert-butylcatechol (VIII), 10-ethoxy-9-phenanthrol (Ia), and 10-methyl-9-phenanthrol (Ib) has been investigated.All products may be accountable through the transfer of O2 from the 4a-FlEtO2- reactant to the phenolate anions with the production of reduced flavin anion (FlEt-) and a hydroperoxycyclohexadienone.From VIII- (t-BuOH) there was obtained 3,5-di-tert-butyl-o-quinone (IX) and Ib- yielded (t-BuOH or CH2CN) 10-hydroxy-10-methyl-9,10-dihydro-9-phenanthrone (IIIb), while Ia- provided both 9,10-phenanthrenequinone (V) and monoethyl 1,1'-diphenate (IVa) (the ratio of V:IVa being solvent dependent).The mechanisms for the decomposition of intermediate peroxide anions to products are discussed.The conversion of Ia- to IVa by oxygen transfer from 4a-FlEtO2- amounts to a catalysis by FlEt- of the reaction of 3O2 with Ia and serves as a biomimetic reaction of flavoenzyme dioxygenase.The kinetic for the reaction of VIII- with 4a-FlEtO2- require the formation of an intermediate.Since the rate constants for the reaction of both VIII- and 2,6-di-tert-butyl-4-methylphenolate anion with 4a-FlEtO2- are identical under saturating conditions by these phenolate ions, it is concluded that the intermediate is formed in a unimolecular reaction from 4a-FlEtO2- (k = 0.36 s-) as in eq 19.Dissociation of 4a-FlEtO2- to FlEt-+ O2 and reaction of phenolate ions with O2 may be discounted since the second-order rate constants for the reaction of phenolate ions with O2 are less than required for the kinetic competency of this process.Dissociation of 4a-FlEtO2- to yield neutral flavin radical (FlEt.) + O2-. followed by reduction of FlEt. by fenolate ion to provide FlEt- and phenoxy radical with the coupling of the latter with O2-. is also improbable.Thus, though the second-order rate constants for 1e- reduction of FlEt. by the various phenolate species are sufficiently large to allow the kinetic competency of this step, there exists no evidence that O2-. can couple with any radical species to provide a hydroperoxide.The oxygen-donating intermediate formed from 4a-FlEtO2- is suggested to be the 4a,10-dioxetane (XII) or an oxygen molecule more loosely associated with FlEt-.The equilibrium constant for the formation of such an intermediate may be as small as 10-5 if the rate of reaction of phenolate ion with this species approaches a diffusion-controlled process.