Russian Journal of Organic Chemistry p. 518 - 521 (2007)
Update date:2022-08-03
Topics:
Terent'ev
Vasil'eva
Chakhovskaya
Mysova
Kochetkov
The system Fe(CO)5-HMPA effectively promotes diastereoselective reductive dimerization of aromatic aldehydes to the corresponding pinacols having preferentially or exclusively dl configuration. In the reaction with pentafluorobenzaldehyde, the product structure strongly depends on the presence of traces of moisture in the reaction system. Nauka/Interperiodica 2007.
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(2008)
