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24082-11-9

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24082-11-9 Usage

Chemical Properties

clear colorless to light yellow liquid

Check Digit Verification of cas no

The CAS Registry Mumber 24082-11-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,4,0,8 and 2 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 24082-11:
(7*2)+(6*4)+(5*0)+(4*8)+(3*2)+(2*1)+(1*1)=79
79 % 10 = 9
So 24082-11-9 is a valid CAS Registry Number.
InChI:InChI=1/C8H20O2Si2/c1-11(2,3)7-8(9)10-12(4,5)6/h7H2,1-6H3

24082-11-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name trimethylsilyl 2-trimethylsilylacetate

1.2 Other means of identification

Product number -
Other names Trimethylsilylessigsaeuretrimethylsilylester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:24082-11-9 SDS

24082-11-9Relevant articles and documents

REINVESTIGATION OF THE REACTION OF LITHIUM TRIMETHYLSILYL ACETATE ENOLATE WITH CHLOROTRIMETHYLSILANE

Bellassoued, Moncef,Gaudemar, Marcel

, p. 209 - 212 (1990)

Reaction of lithium trimethylsilyl acetate enolate with chlorotrimethylsilane affords bis(trimethylsilyl) ketene acetal 1 or trimethylsilyl α-trimethylsilylated acetate 2 depending on the reaction conditions.

Two-carbon homologation of aldehydes via silyl ketene acetals: A new stereoselective approach to (E)-alkenoic acids

Bellassoued, Moncef,Lensen, Nathalie,Bakasse, Mina,Mouelhi, Sinda

, p. 8785 - 8789 (2007/10/03)

Aldehydes are converted into (E)-α,β-unsaturated carboxylic acids using C,O,O-tris(trimethylsilyl)ketene acetal 1. This organosilicon reagent is easily generated from trimethylsilyl acetate, LDA, and chlorotrimethylsilane. The effectiveness of the reaction has been explored for a large variety of aldehydes with Lewis acids and fluorides as catalysts.

α-SILYL TRIMETHYLSILYLESTERS FROM ALIPHATIC CARBOXYLIC ACID DIANIONS

Bellassoued, M.,Dubois, J. E.,Bertounesque, E.

, p. 263 - 266 (2007/10/02)

The synthesis of α-silyl trimethylsilyl esters from aliphatic carboxylic acid dianions is reported.The results indicate kinetic and thermodynamic control of silylation of acid dianions.

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