24334-81-4

Upstream product

• 107-15-3 ethylenediamine 
• 93-91-4 1-phenylbutan-1,3-dione 
• 32398-66-6 1-phenylbut-2-yn-1-ol 
• 70769-72-1 1-phenyl-3-ethylsulfenyl-2-buten-1-one 

Downstream Products

• 1094451-80-5 C₂₈H₂₆N₂O₃ 
• 139120-26-6 (Z)-2-(4-Bromo-phenylazo)-3-{2-[(Z)-2-(4-bromo-phenylazo)-1-methyl-3-oxo-3-phenyl-propenylamino]-ethylamino}-1-phenyl-but-2-en-1-one 
• 139120-25-5 (Z)-2-(4-Chloro-phenylazo)-3-{2-[(Z)-2-(4-chloro-phenylazo)-1-methyl-3-oxo-3-phenyl-propenylamino]-ethylamino}-1-phenyl-but-2-en-1-one 
• 139120-24-4 (Z)-3-{2-[(Z)-1-Methyl-2-(4-nitro-phenylazo)-3-oxo-3-phenyl-propenylamino]-ethylamino}-2-(4-nitro-phenylazo)-1-phenyl-but-2-en-1-one 

Relevant academic research and scientific papers

Standard enthalpies of formation of N,N'-ethylenebis(4-aminopent-3-en-2-one) and N,N'-ethylenebis(3-amino-1-phenylbut-2-en-1-one)

The standard (p0 = 0.1 MPa) molar enthalpies of combustion, at the temperature 298.15 K for crystalline N,N'-ethylenebis(4-aminopent-3-en-2-one), 2, H2ACACEN, and N,N'-ethylenebis(3-amino-1-phenylbut-2-en-1-one), H2BZACEN,

Nano-SiO2 catalyzed synthesis of β-enaminones under solvent free conditions

Nano-SiO2 efficiently catalyzed the synthesis of β-enaminones using direct condensation of various (cyclic and acyclic) β-diketones with aromatic and aliphatic amines under solvent-free conditions. This eco-friendly catalyst can be recovered and reused without significant loss of activity. This methodology provides a simple synthetic route to enaminones in excellent yields at room temperature. Graphical abstract: [Figure not available: see fulltext.]

Influence of the structure on the antioxidant activity of tetradentate schiff bases and their copper(II) complexes: Possible mechanisms

The influence of the structure on the antioxidant activity of a series of Schiff bases and their copper(II) complexes as well as possible mechanisms of antioxidant activity were investigated. Schiff bases are derived from the condensation of ethane-1,2-di

A green solventless protocol for the synthesis of β-Enaminones and β -Enamino esters using silica sulfuric acid as a highly efficient, heterogeneous and reusable catalyst

Silica sulfuric acid is utilized as a green, highly efficient, heterogeneous and recyclable catalyst for the preparation of β-enaminones and β -enamino esters from amines and β -dicarbonyl compounds under solvent-free conditions at 80 °C. Using this method, the title compounds are produced in high to excellent yields and in short reaction times.

Silica-supported LiHSO4 as a highly efficient, heterogeneous and reusable catalytic system for the solvent-free synthesis of β-enaminones and β-enamino esters

A highly efficient, simple and green procedure for the synthesis of β-enaminones and β-enamino esters is described. The reaction of aromatic and aliphatic amines with β-dicarbonyl compounds using catalytic amount of silica-supported LiHSO4 (LiHSO4/SiO2) under solvent-free conditions at 80 °C affords the title compounds in high to excellent yields and in short reaction times.

Cerium(III) chloride heptahydrate (CeCl3·7H2O) as an efficient enamination catalyst in aqueous media

Cerium(III) chloride heptahydrate CeCl3·H2O catalyzes enamination of β-dicarbonyl compounds with primary amines in aqueous medium at room temperature to afford the corresponding β-enamino ketones with high chemoselectivity.

Enamination of β-dicarbonyl compounds catalyzed by CeCl 3·7H2O at ambient conditions: Ionic liquid and solvent-free media

Enamination of a wide various primary amines was successfully carried out in the presence of catalytic amounts of cerium chloride heptahydrate in ionic liquid and solvent-free conditions as 'green' media under mild reaction conditions.

Reactions of β-Sulfenyl α,β-Unsaturated Ketones with Guanidine, Amidines and Diamines

β-Sulfenyl α,β-unsaturated ketones 1a-c reacted with guanidine or amidines to give pyrimidine derivatives 3 in 14-76percent yields.Treatment of ketones 1 with diamines such as ethylenediamine and o-phenylenediamine afforded the seven-membered heterocycles, 2,3-dihydro-1,4-diazepine 5 and 2,3-benzo-1,4-diazepines 8a-c.

Oxidative S-Dealkylation Reaction of Sulfide Catalyzed by Co(II)(bzacen)

In the oxygenation reaction of alkyl sulfides with Co(II)(bzacen)-O2 system, oxidative S-C bond cleavage (S-dealkylation) was found to take place exclusively.The reactivity of S-dealkylation reaction was dependent markedly on both acidity of α-methylene and steric hindrance of alkyl sulfide.The peroxo-Co(III) species is presumed to be the intermediate in this S-dealkylation reaction.