24334-81-4

Basic information

• Product Name: N,N'-bis(2-benzoyl-1-methylethylidene)ethylenediamine
• Synonyms: N,N'-bis(2-benzoyl-1-methylethylidene)ethylenediamine
• CAS NO: 24334-81-4
• Molecular Weight: 348.445
• Mol File: 24334-81-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: N,N'-bis(2-benzoyl-1-methylethylidene)ethylenediamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-bis(2-benzoyl-1-methylethylidene)ethylenediamine(24334-81-4)
• EPA Substance Registry System: N,N'-bis(2-benzoyl-1-methylethylidene)ethylenediamine(24334-81-4)

Safety Data

• Hazardous Substances Data: 24334-81-4(Hazardous Substances Data)

Upstream product

• 32398-66-6 1-phenylbut-2-yn-1-ol 
• 70769-72-1 1-phenyl-3-ethylsulfenyl-2-buten-1-one 
• 107-15-3 ethylenediamine 
• 93-91-4 1-phenylbutan-1,3-dione 

Downstream Products

• 139120-26-6 (Z)-2-(4-Bromo-phenylazo)-3-{2-[(Z)-2-(4-bromo-phenylazo)-1-methyl-3-oxo-3-phenyl-propenylamino]-ethylamino}-1-phenyl-but-2-en-1-one 
• 139120-25-5 (Z)-2-(4-Chloro-phenylazo)-3-{2-[(Z)-2-(4-chloro-phenylazo)-1-methyl-3-oxo-3-phenyl-propenylamino]-ethylamino}-1-phenyl-but-2-en-1-one 
• 139120-24-4 (Z)-3-{2-[(Z)-1-Methyl-2-(4-nitro-phenylazo)-3-oxo-3-phenyl-propenylamino]-ethylamino}-2-(4-nitro-phenylazo)-1-phenyl-but-2-en-1-one 
• 1094451-80-5 C₂₈H₂₆N₂O₃ 

Relevant articles and documents

Standard enthalpies of formation of N,N'-ethylenebis(4-aminopent-3-en-2-one) and N,N'-ethylenebis(3-amino-1-phenylbut-2-en-1-one)

The standard (p0 = 0.1 MPa) molar enthalpies of combustion, at the temperature 298.15 K for crystalline N,N'-ethylenebis(4-aminopent-3-en-2-one), 2, H2ACACEN, and N,N'-ethylenebis(3-amino-1-phenylbut-2-en-1-one), H2BZACEN,

Nano-SiO2 catalyzed synthesis of β-enaminones under solvent free conditions

Nano-SiO2 efficiently catalyzed the synthesis of β-enaminones using direct condensation of various (cyclic and acyclic) β-diketones with aromatic and aliphatic amines under solvent-free conditions. This eco-friendly catalyst can be recovered and reused without significant loss of activity. This methodology provides a simple synthetic route to enaminones in excellent yields at room temperature. Graphical abstract: [Figure not available: see fulltext.]

A green solventless protocol for the synthesis of β-Enaminones and β -Enamino esters using silica sulfuric acid as a highly efficient, heterogeneous and reusable catalyst

Silica sulfuric acid is utilized as a green, highly efficient, heterogeneous and recyclable catalyst for the preparation of β-enaminones and β -enamino esters from amines and β -dicarbonyl compounds under solvent-free conditions at 80 °C. Using this method, the title compounds are produced in high to excellent yields and in short reaction times.

Cerium(III) chloride heptahydrate (CeCl3·7H2O) as an efficient enamination catalyst in aqueous media

Cerium(III) chloride heptahydrate CeCl3·H2O catalyzes enamination of β-dicarbonyl compounds with primary amines in aqueous medium at room temperature to afford the corresponding β-enamino ketones with high chemoselectivity.