24398-53-6 Usage
Organic compound
It is an organic compound meaning it is primarily composed of carbon, hydrogen, and other elements such as nitrogen in this case.
Usage in chemistry and pharmaceuticals
1-tert-butyl-2-(diphenylmethylidene)hydrazine is commonly used in the fields of chemistry and pharmaceuticals for various purposes, including the synthesis of other organic compounds.
Hydrazine functional group
It is known for its hydrazine functional group (N-N) a functional group consisting of two nitrogen atoms bonded together, which plays a key role in its reactivity and properties.
tert-Butyl group
The presence of a tert-butyl group (C4H9) a type of alkyl group derived from isobutane, contributes to the structure and properties of the compound.
Diphenylmethylidene group
The presence of a diphenylmethylidene group (C6H5-C-) a type of aryl group derived from toluene, also contributes to the structure and properties of the compound.
Chemical reactions and processes
1-tert-butyl-2-(diphenylmethylidene)hydrazine is used in various chemical reactions and processes, playing a role in the synthesis of other organic compounds.
Toxicity and hazardous nature
It is important to handle 1-tert-butyl-2-(diphenylmethylidene)hydrazine with care, as hydrazines can be toxic and potentially hazardous if not used properly.
Check Digit Verification of cas no
The CAS Registry Mumber 24398-53-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,4,3,9 and 8 respectively; the second part has 2 digits, 5 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 24398-53:
(7*2)+(6*4)+(5*3)+(4*9)+(3*8)+(2*5)+(1*3)=126
126 % 10 = 6
So 24398-53-6 is a valid CAS Registry Number.
24398-53-6Relevant academic research and scientific papers
Palladium-catalyzed synthesis of aryl ketones by coupling of aryl bromides with an acyl anion equivalent
Takemiya, Akihiro,Hartwig, John F.
, p. 14800 - 14801 (2008/02/05)
Palladium-catalyzed couplings of aryl bromides with N-tert-butylhydrazones as acyl anion equivalents to form aryl ketones are reported. The coupling process occurs at the C-position of hydrazones to form N-tert-butyl azo compounds. Isomerization of these azo compounds to the corresponding hydrazones, followed by hydrolysis, gave the desired mixed alkyl aryl ketones. The selectivity of C- versus N-arylation was strongly influenced by the substituent on nitrogen. Arylation at carbon occurred with N-tert-butylhydrazones, whereas N-arylation occurred with N-arylhydrazones. The arylation of hydrazones containing primary and secondary alkyl groups, as well as aryl groups, gave the desired ketones in good yields after hydrolysis. Functional groups on the aromatic ring, such as alkoxy, cyano, trifluoromethyl, carboalkoxy, carbamoyl, and keto groups, were tolerated. This reaction likely occurs by C-C bond-forming reductive elimination from an intermediate containing an η1-diazaallyl ligand. Copyright
Azo Anions in Synthesis: α-Amino Carbanion Equivalents from t-Butyldiphenylmethylhydrazones
Baldwin, Jack E.,Adlington, Robert M.,Newington, Ian M.
, p. 176 - 178 (2007/10/02)
α-Amino carbanion equivalents (=C(1-)NH2) and α-hydrazino anion equivalents (=C(1-)NHNH2) are readily accessible from the C-alkylation products of t-butyldiphenylmethylhydrazones; these azoalkanes can be efficiently transformed into amines, hydrazines, and also alkanes under mild reaction conditions.
