32064-67-8

Basic information

• Product Name: tert-Butyl hydrazine
• Synonyms: Hydrazine,(1,1-dimethylethyl)-
• CAS NO: 32064-67-8
• Molecular Formula: C₄H₁₂N₂
• Molecular Weight: 88.15
• Mol File: 32064-67-8.mol
• Article Data: 12

Chemical Properties

• Melting Point: 85 °C
• Boiling Point: 135°Cat760mmHg
• Flash Point: 35.8°C
• Appearance: /
• Density: 0.823g/cm³
• PKA: 8.92±0.70(Predicted)
• CAS DataBase Reference: tert-Butyl hydrazine(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl hydrazine(32064-67-8)
• EPA Substance Registry System: tert-Butyl hydrazine(32064-67-8)

Safety Data

• Hazardous Substances Data: 32064-67-8(Hazardous Substances Data)

Usage

General Description

Tert-butyl hydrazine is a colorless, flammable liquid with a faint amine-like odor. It is a highly reactive compound that is primarily used as a fuel in rocket propulsion systems. Tert-butyl hydrazine is a strong reducing agent and can react violently with oxidizing agents. Exposure to tert-butyl hydrazine can cause irritation to the eyes, skin, and respiratory system, and prolonged or high-level exposure can lead to more serious health effects. Due to its hazardous nature, tert-butyl hydrazine is handled with extreme caution and is used primarily in industrial and research settings.

Upstream product

• 507-20-0 tertiary butyl chloride 
• 24398-53-6 benzophenone-tert-butylhydrazone 
• 75-65-0 tert-butyl alcohol 
• 7400-27-3 tertbutylhydrazine hydrochloride 
• 7732-18-5 water 
• 38511-18-1 1-tert-butyl-3-methyl-diaziridine 
• 6939-25-9 3-(t-butyl)sydnone 
• 60295-52-5 tert-butyl 2-(tert-butyl)hydrazinecarboxylate 
• 93807-28-4 di-tert-butyl 1-(tert-butyl)hydrazine-1,2-dicarboxylate 
• 75-16-1 methylmagnesium bromide 
• 627-70-3 propan-2-one azine 
• 60-29-7 diethyl ether 
• 75-64-9 tert-butylamine 

Downstream Products

• 25149-46-6 tert.-Butylazo-isobutyronitril 
• 162752-59-2 N-(3,5-Dimethylbenzoyl)-N-tert-Butyl-Hydrazine 
• 1243251-76-4 1-(1,1-dimethylethyl)-3-phenyl-1H-pyrazole-5-carboxylic acid 
• 175277-09-5 1-(1,1-dimethylethyl)-3-methyl-1H-pyrazole-5-carboxylic acid 
• 1020724-17-7 1-(1,1-dimethylethyl)-3-propyl-1H-pyrazole-5-carboxylic acid 
• 112225-93-1 2-iodobenzoic acid N'-tert-butylhydrazide 
• 1358761-80-4 2-chloro-5-fluorobenzoic acid N'-t-butylhydrazide 
• 112225-90-8 N-tert-butyl-N-(2-chlorobenzoyl)hydrazine 
• 112226-01-4 C₁₁H₁₅BrN₂O 
• 1381843-60-2 C₂₁H₂₄N₂ 
• 187795-43-3 1-(tert-butyl)-3-cyclopropyl-1H-pyrazol-5-amine 
• 1215219-97-8 C₁₃H₁₅FN₂O 
• 1167442-54-7 2-tert-butylphthalazin-1(2H)-one 

Relevant articles and documents

A method for synthesis of tertiary butyl jing

The invention provides a method for synthesis of tertiary butyl jing, this method is in the inert gas under the protection of the tertiary butyl alcohol and hydrazine hydrate under the action of catalyst and under a certain temperature for carrying out the alkylation reaction, butadiene butyl jing, after the reaction the reaction liquid to get the uncle butyl jing the finished product, the reaction catalyst is D002 macroporous strong acid cation exchange resin. Compared with the prior art, the invention taking tert butyl alcohol and hydrazine as raw material, one-step synthesis of uncle butyl jing, its simple process steps, high requirements on equipment, equipment investment is small, the reaction yield is high, production cost is low, waste is discharged little, is an environment-friendly production process.

Uncle butyl jing synthetic method

The invention provides a method for synthesis of tertiary butyl jing, this method is in the inert gas under the protection of the tertiary butyl alcohol and hydrazine hydrate under the action of catalyst and under a certain temperature for carrying out the alkylation reaction, butadiene butyl jing, after the reaction the reaction liquid to get the uncle butyl jing the finished product, the catalyst is a ZnO/Al reaction2 O3 Composite catalyst. Compared with the prior art, the invention taking tert butyl alcohol and hydrazine as raw material, one-step synthesis of uncle butyl jing, its simple process steps, high requirements on equipment, equipment investment is small, the reaction yield is high, production cost is low, waste is discharged little, is an environment-friendly production process.

N-tert-butyl triazolylidenes: Catalysts for the enantioselective (3+2) annulation of α,β-unsaturated acyl azoliums

But(yl) not futile: A range of N-tert-butyl-substituted triazolylidene N-heterocyclic carbenes have been prepared. Of these, the morpholinone-derived catalyst (1) proved best suited to the enantioselective synthesis of cyclopentanes from donor-acceptor cy