51980-05-3

Basic information

• Product Name: 3-(4-CYANOPHENYL)-1-PROPENE
• Synonyms: 3-(4-CYANOPHENYL)-1-PROPENE
• CAS NO: 51980-05-3
• Molecular Formula: C₁₀H₉N
• Molecular Weight: 143.19
• Mol File: 51980-05-3.mol
• Article Data: 32

Chemical Properties

• Boiling Point: 244.766°C at 760 mmHg
• Flash Point: 101.801°C
• Appearance: /
• Density: 0.991g/cm³
• Vapor Pressure: 0.03mmHg at 25°C
• Refractive Index: 1.535
• CAS DataBase Reference: 3-(4-CYANOPHENYL)-1-PROPENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-CYANOPHENYL)-1-PROPENE(51980-05-3)
• EPA Substance Registry System: 3-(4-CYANOPHENYL)-1-PROPENE(51980-05-3)

Safety Data

• Hazardous Substances Data: 51980-05-3(Hazardous Substances Data)

Usage

General Description

3-(4-Cyanophenyl)-1-propene is a chemical compound with the molecular formula C10H9N. It is an unsaturated hydrocarbon that contains a cyanophenyl group and a propene group. 3-(4-CYANOPHENYL)-1-PROPENE is commonly used in organic synthesis and chemical research as a starting material for the production of various other compounds. It is a colorless liquid with a strong odor and is considered to be flammable. It is important to handle this chemical with caution and to follow proper safety protocols when working with it in a laboratory or industrial setting.

InChI:InChI=1/C10H9N/c1-2-3-9-4-6-10(8-11)7-5-9/h2,4-7H,1,3H2

Upstream product

• 556-56-9 allyl iodid 
• 623-00-7 4-bromobenzenecarbonitrile 
• 106-95-6 allyl bromide 
• 2252-32-6 4-cyanophenyldiazonium tetrafluoroborate 
• 762-72-1 allyl-trimethyl-silane 
• 591-87-7 Allyl acetate 
• 623-26-7 terephthalonitrile 
• 24850-33-7 allyltributylstanane 
• 126747-14-6 4-cyanophenylboronic acid 
• 3058-39-7 4-iodobenzonitrile 
• 3959-07-7 4-Bromobenzylamine 
• 77785-94-5 4-(2-propenyl)benzaldehyde 
• 1122-91-4 4-bromo-benzaldehyde 
• 1184723-05-4 2-(4-allylphenyl)-1,3-dioxolane 

Downstream Products

• 1610026-10-2 (E)-4-(3-azidoprop-1-enyl)benzonitrile 
• 1610026-30-6 (E)-4-phenyl-1-(3-(4-vinylphenyl)allyl)-1H-1,2,3-triazole 
• 101478-66-4 4-(4-oxobutyl)benzonitrile 
• 57918-88-4 3-(4-cyanophenyl)-2-methylpropanal 
• 41917-85-5 p-cyanocinnamaldehyde 
• 1150644-93-1 N-hydroxy-4-(2-propen-1-yl)benzenecarboximidamide 
• 1176891-05-6 (E)-methyl 3-(4-cyanophenyl)allyl(tosyl)carbamate 
• 1073426-81-9 C₁₃H₁₂N₂O₄ 
• 1073426-57-9 (E)-methyl 5-(4-cyanophenyl)-2-nitropent-4-enoate 

Relevant articles and documents

Photoinduced Cross-Coupling of Aryl Iodides with Alkenes

A protocol for photoinduced cross-coupling of aryl iodides having polar π-functional groups or elongated π-conjugation with alkenes has been developed. The radical cascade mechanism involving generation of aryl radicals via C-I bond homolysis of photoexcited aryl iodides and their subsequent addition to alkenes is proposed. The method enables iodide-selective cross-coupling over other halogen leaving groups with functional group compatibility on both arene and alkene motifs.

Manganese catalyzed dehydrogenative silylation of alkenes: Direct access to allylsilanes

Dehydrogenative silylation of alkenes with silanes to produce allylsilanes is achieved through manganese catalysis with a wide scope of substrate tolerance. This transformation involves silane radicals initiated by manganese complex without additional oxidant additives. It offers a general, convenient and practical protocol with excellent functional group compatibility and gram-scale capacity for the modular synthesis of allylsilanes.

Visible light promoted metal- and photocatalyst-free synthesis of allylarenes

The metal- and photocatalyst-free synthesis of substituted allylarenes has been carried out under visible light driven conditions. The process was based on the photogeneration of aryl radicals from arylazo sulfones and their ensuing reaction with allyl sulfones. The developed procedure was very efficient when using substrates bearing electron-withdrawing groups, and allowed for the preparation of α-benzyl styrenes and 2-benzyl acrylates in good yields.