512779-61-2Relevant academic research and scientific papers
Regioselective, nucleophilic carbon-carbon bond formation at the C4-position of indoles initiated by the aromatic Pummerer-type reaction
Akai, Shuji,Kawashita, Norihito,Wada, Yasufumi,Satoh, Hideharu,Alinejad, Anahita Hessamian,Kakiguchi, Keisuke,Kuriwaki, Ikumi,Kita, Yasuyuki
, p. 1881 - 1884 (2006)
The treatment of the 5-(phenylsulfinyl)indoles with trifluoroacetic anhydride in the presence of carbon nucleophiles achieved the title reactions with complete regioselectivity.
Regioselective synthesis of 2,3,5-trisubstituted indoles from p-sulfinylaniline by dual use of the sulfinyl group
Akai, Shuji,Kawashita, Norihito,Morita, Nobuyoshi,Nakamura, Yuka,Iio, Kiyosei,Kita, Yasuyuki
, p. 75 - 78 (2007/10/03)
A novel and convergent synthesis of 2,3,5-trisubstituted indoles (6) from p-sulfinylaniline (1) is described. The single p-sulfinyl group was repeatedly employed in two ways; viz., the construction of the 2,3-disubstituted indole/indoline skeleton and the
