244229-40-1Relevant academic research and scientific papers
A novel axially dissymmetric ligand with chiral 2,2,2-trifluoro-1- hydroxyethyl groups
Omote, Masaaki,Kominato, Akane,Sugawara, Michi,Sato, Kazuyuki,Ando, Akira,Kumadaki, Itsumaro
, p. 5583 - 5585 (1999)
Novel axially dissymmetric ligands (1) with two more chiral carbons were synthesized through homo-coupling of o-bromo-(R or S)-(2,2,2-trifluoro-1- acetoxyethyl)benzene. A high asymmetric induction was accomplished using 5 mol% of the Ti complex of this li
