A novel axially dissymmetric ligand with chiral 2,2,2-trifluoro-1- hydroxyethyl groups

DOI: 10.1016/S0040-4039(99)01083-7

Source and publish data:

Tetrahedron Letters p. 5583 - 5585 (1999)

Update date:2022-07-30

Topics:

Authors:

Omote, Masaaki

Kominato, Akane

Sugawara, Michi

Sato, Kazuyuki

Ando, Akira

Kumadaki, Itsumaro

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Article abstract of DOI:10.1016/S0040-4039(99)01083-7

Novel axially dissymmetric ligands (1) with two more chiral carbons were synthesized through homo-coupling of o-bromo-(R or S)-(2,2,2-trifluoro-1- acetoxyethyl)benzene. A high asymmetric induction was accomplished using 5 mol% of the Ti complex of this li

Full text of DOI:10.1016/S0040-4039(99)01083-7

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Product name:o-bromo-(S)-(2,2,2-trifluoro-1-acetoxyethyl)benzene

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