Tetrahedron Letters p. 5583 - 5585 (1999)
Update date:2022-07-30
Topics:
Omote, Masaaki
Kominato, Akane
Sugawara, Michi
Sato, Kazuyuki
Ando, Akira
Kumadaki, Itsumaro
Novel axially dissymmetric ligands (1) with two more chiral carbons were synthesized through homo-coupling of o-bromo-(R or S)-(2,2,2-trifluoro-1- acetoxyethyl)benzene. A high asymmetric induction was accomplished using 5 mol% of the Ti complex of this li
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