24423-97-0

Usage

Uses

Used in Organic Synthesis:
((Z)-1-benzyl-2-phenylethenyl)benzene is used as a building block in the synthesis of various organic compounds due to its unique structure and reactivity.
Used in Research:
((Z)-1-benzyl-2-phenylethenyl)benzene is used as a research compound to study its properties and potential applications in various fields.
Used in Dye Production:
((Z)-1-benzyl-2-phenylethenyl)benzene is used as a precursor in the production of dyes due to its ability to absorb and emit light.
Used in Optical Brighteners:
((Z)-1-benzyl-2-phenylethenyl)benzene is used as a component in the formulation of optical brighteners, which enhance the appearance of materials by reflecting light.
Used in Pharmaceutical Industry:
((Z)-1-benzyl-2-phenylethenyl)benzene is used as a starting material for the synthesis of pharmaceutical compounds, potentially contributing to the development of new drugs.
Used in Organic Light Emitting Diodes (OLEDs):
((Z)-1-benzyl-2-phenylethenyl)benzene is used as a material in the development of organic light emitting diodes, which are used in various electronic devices for display and lighting applications.

Upstream product

• 871889-35-9 2,2,3-triphenyl propanol 
• 5472-27-5 1,2,3-triphenyl-propan-2-ol 
• 60-29-7 diethyl ether 
• 124-38-9 carbon dioxide 
• 59405-90-2 (+/-)-3-methoxy-1t.2.3-triphenyl-propene-⁽¹⁾ 
• 110-86-1 pyridine 
• 7719-09-7 thionyl chloride 
• 109242-28-6 (+/-)-1.2c_F.3-triphenyl-propanol-(1r_F) 
• 109242-28-6 (+/-)-1.2t_F.3-triphenyl-propanol-(1r_F) 
• 2996-92-1 phenyl trimethylsiloxane 
• 98-88-4 benzoyl chloride 

Downstream Products

• 50403-40-2 2-benzyl-2,3-diphenyl-oxirane 
• 18636-54-9 1,2-diphenyl-1H-indene 
• 98-88-4 benzoyl chloride 
• 109242-28-6 (+/-)-1.2t_F.3-triphenyl-propanol-(1r_F) 
• 19019-00-2 1,2,3-Triphenyl-propen-⁽¹⁾-nitronsaeure 
• 19018-99-6 1-nitro-1,2,3-triphenyl-propene 
• 19019-01-3 1,2,3-Triphenyl-3-nitro-propen-1 
• 4746-79-6 1-(2'-benzoylphenyl)-2-phenylethane-1,2-dione 
• 261171-05-5 (E)-3-azido-1,2,3-triphenyl-1-propene 
• 57015-16-4 (E)-1,2,3-triphenylprop-2-en-1-ol 
• 261171-07-7 (E)-3-bromo-1,2,3-triphenyl-1-propene 
• 19018-98-5 1-Nitro-1,2,3-triphenyl-propanol-⁽²⁾ 
• 19018-97-4 1,2-Dinitro-1,2,3-triphenyl-propan 

Relevant academic research and scientific papers

Palladium-catalyzed hiyama cross-couplings of aryl arenesulfonates with arylsilanes

Palladium-catalyzed efficient Hiyama cross-coupling reaction of aryl arenesulfonate with arylsilane is described. The desired carbon-carbon bond formation proceeds under mild conditions with good functional group tolerance. Copyright

REDUCTIVE COUPLING OF BENZOIC ACID HALIDES AND ESTERS USING LOW-VALENT TITANIUM

The reductive coupling of (substituted) benzoic acid chlorides and esters is achieved using low-valent titanium, generated from TiCl3 and LiAlH4.Both acid chlorides and esters seem to follow the same two reaction pathways: one path via tolanes to stilbenes, the other via benzils to complex mixtures of products arising from reduction and further coupling reactions.Although the exact product balance depends upon the reaction conditions the major product is (substituted) cis-stilbene.

Conformations and Rotational Barriers of 1,3-Diphenylallyllithium Compounds

The phenyl substituents of the 1,3-diphenylallyl anions 10 (gegenion lithium, solvent tetrahydrofuran) can exist in the exo,exo-, endo,exo- and/or endo,endo-conformations.We have investigated the influence of substituents R at C2 on the equilibria of these solvent separated ion pairs.While 10a (R = H) is the only one to exist predominantly in the exo,exo-conformation, and in 10b and c (R = CH3 and CN, respectively) the endo,exo-conformers predominate, in 10d, e and f (R = C2H5, C6H5 and iPr, respectively) there is increasing preference for the endo,endo-conformation, which in 10g (R = tBu) is the dominant (>/= 95percent) conformation.A vast congestion in the endo,endo-conformation is avoided by a rotation of the phenyl rings out of the plane of the allyl carbon atoms, and an expansion of the sp2 angles in the allyl moiety.The rotational barriers around the allyl anion bonds decrease from 19.1 kcal*mol-1 (10a) to 12.5 kcal*mol-1 (10f).Since this trend parallels to the above mentioned shift of the equilibria, it is due to ground state effects.The rotational barriers are only slightly (10a,b) if at all influenced by gegenion effects, which is in sharp contrast to the parent allyl "anion".Therefore, the rotational barriers of the allyl anions 10 are qualified for a comparison with the corresponding radicals and cations.Furthermore, with ΔG(excit)273 deg C = 19.1 kcal*mol-1 as a lower limit value for the rotational barrier of the parent allyl anion, one can estimate that the true value of this species must be close to barriers calculated with STO-3G and 4-3l-G programs (ca. 26 kcal*mol-1).