(Z)-1,2,3-Triphenylpropene

Base Information

• Chemical Name: (Z)-1,2,3-Triphenylpropene
• CAS No.: 24423-97-0
• Molecular Formula: C21H18
• Molecular Weight: 270.374
• NSC Number: 337988
• DSSTox Substance ID: DTXSID60420689
• Nikkaji Number: J1.239.535C,J1.862.091J
• Wikidata: Q82231994
• Mol file: 24423-97-0.mol

Synonyms:NSC337988;24423-97-0;(Z)-1,2,3-Triphenylpropene;1,2,3-Triphenyl-1-propene;DTXSID60420689;AKOS004905378;NSC-337988

Chemical Property of (Z)-1,2,3-Triphenylpropene

Chemical Property:

• Vapor Pressure: 1.95E-05mmHg at 25°C
• Boiling Point: 373.2°Cat760mmHg
• Flash Point: 175°C
• Density: 1.067g/cm³
• XLogP3: 6.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 270.140850574
• Heavy Atom Count: 21
• Complexity: 309

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)CC(=CC2=CC=CC=C2)C3=CC=CC=C3
• Isomeric SMILES: C1=CC=C(C=C1)C/C(=C/C2=CC=CC=C2)/C3=CC=CC=C3

Technology Process of (Z)-1,2,3-Triphenylpropene

There total 13 articles about (Z)-1,2,3-Triphenylpropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1,2,3-triphenyl-propan-2-ol (5472-27-5) → 1,2,3-triphenyl-1-propene (24423-97-0)

Guidance literature:

With sulfuric acid; In acetic acid; at 100 ℃; for 2h;

Reference yield: 80.0%

C22H20O3Si + phenyl trimethylsiloxane (2996-92-1,46143-12-8) → 1,2,3-triphenyl-1-propene (24423-97-0)

Guidance literature:

With dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl; tetrabutyl ammonium fluoride; palladium diacetate; In tetrahydrofuran; at 80 ℃; Inert atmosphere;

DOI:10.1021/ja804672m

Reference yield:

benzoyl chloride (98-88-4) → phenyl benzyl ketone (451-40-1) + cis-stilben (645-49-8) + 1,2,3-triphenyl-1-propene (24423-97-0) + diphenyl acetylene (501-65-5)

Guidance literature:

With lithium aluminium tetrahydride; titanium(III) chloride; In tetrahydrofuran; for 24h; Title compound not separated from byproducts; Heating;

upstream raw materials:

2,2,3-triphenyl propanol

1,2,3-triphenyl-propan-2-ol

benzoyl chloride

diethyl ether

Downstream raw materials:

2-benzyl-2,3-diphenyl-oxirane

1,2-diphenyl-1H-indene

1,2-Dinitro-1,2,3-triphenyl-propan

1-Nitro-1,2,3-triphenyl-propanol-⁽²⁾