24454-89-5

Usage

Physical Properties

colorless liquid, sweet floral odor, highly flammable

Uses

production of pharmaceuticals, fragrances, building block for organic compounds

Health Risks

potential mutagen, respiratory irritant, should be avoided

Environmental Risks

potential risk for environmental contamination, precautions should be taken to prevent release into the environment

Upstream product

• 689-97-4 3-buten-1-yne 
• 64-19-7 acetic acid 
• 463-51-4 Ketene 
• 78-94-4 methyl vinyl ketone 
• 108-22-5 Isopropenyl acetate 
• 108-24-7 acetic anhydride 

Downstream Products

• 605-32-3 2-hydroxy-9,10-anthraquinone 
• 89005-13-0 Acetic acid 5,8-bis-benzenesulfonylamino-6-methoxy-1,4-dihydro-naphthalen-2-yl ester 
• 81-64-1 1,4-dihydroxy-9,10-anthracenedione 
• 63229-39-0 2-acetoxy-1,4,4a,12a-tetrahydronaphthacene-5,6,11,12-tetrone 
• 78-94-4 methyl vinyl ketone 
• 1198439-30-3 (S)-4-formylcyclohex-1-enyl acetate 

Relevant academic research and scientific papers

Asymmetrie construction of rings A - D of Daphnicyclidin-type alkaloids

[Chemical Equation Presented] The aza-Cope-Mannich reaction and ring-closing metathesis are key steps in the assembly of intermediates containing rings A - D of Daphniphyllum alkaloids of the daphnicyclidin type such as daphnipaxinin and oldhamine A.

Process for the preparation of unsaturated ketones

Ketones, which are intermediates in the synthesis of vitamin A or perfumes, and have the general formula: EQU1 wherein R1 is hydrogen or C1-10 hydrocarbon, R2 and R3 are hydrogen or C1-4 alkyl, R4 and R5 are hydrogen or together form a --CH2 --CH2 --C(CH3)2 -- group, R6 and R7 are hydrogen or C1-10 hydrocarbon, or together with the carbon atom to which they are joined form a hydrocarbon ring of up to 10 carbons, or EQU2 forms a hydrocarbon ring of up to 10 carbons joined through R6 and R8 or R7 and R8, R8 is hydrogen or C1-10 hydrocarbon and n is 0-6, are prepared by reacting an unsaturated halide of formula EQU3 wherein X is halogen, with an enol ester of formula EQU4 wherein R9 is C1-20 hydrocarbon, in the presence of a metal catalyst.