24456-95-9Relevant academic research and scientific papers
Iron-Catalyzed Radical Methylation of Activated Alkenes with tert -Butanol as the Methyl Source
Cao, Shouhao,Ji, Hongfang,Jia, Rui,Ma, Zhiwei,Shen, Liang,Xu, Zhengbao
supporting information, p. 1909 - 1913 (2019/09/30)
A free-radical-initiated methylation/addition/cyclization of N -arylacrylamides and a methylation/addition/elimination of quinines have been developed in which t -BuOH is used as a methyl source. These reactions provide effective and selective methods for the synthesis of various methylated oxindoles and quinones in moderate to good yields.
Kinetic isotope effects for electron-transfer pathways in the oxidative C-H activation of hydrocarbons
Bockman,Hubig,Kochi
, p. 2826 - 2830 (2007/10/03)
Fast hydrogen atom transfers from various methylbenzenes (ArH) to photoactivated quinones Q* show primary kinetic isotope effects k(H)/k(D) of 2.4-5.6. The quantitative effects of added inert salt on the kinetics and on the yields of the intermediate cation radical ArH(+*) demonstrate that hydrogen transfer proceeds via a two-step sequence involving an initial electron transfer to form the ion-radical pair [ArH(+*), Q(-*)] which subsequently undergoes proton transfer according to the electron-transfer mechanism in Scheme 1.
