24580-57-2Relevant academic research and scientific papers
Allylation of cyclohexanones in aqueous media and influence of facial amphiphilic fructopyranosides
Bellomo, Ana,Daniellou, Richard,Plusquellec, Daniel
, p. 4934 - 4936 (2010)
The indium-catalyzed allylation reaction was performed in good yields and short reaction time with various cyclohexanones in water. Aqueous facial amphiphilic carbohydrates solutions were also screened for their potency to modify the stereochemical outcom
Zinc mediated allylation of aldehydes and ketones using allyl bromides and commercial zinc dust. the issue of regio- And stereoselectivity
Majee, Adinath,Das, Asish R.,Ranu, Brindaban C.
, p. 731 - 736 (2007/10/03)
An efficient procedure for the preparation of homoallylic alcohols has been achieved by a simple reaction of an aldehyde or a ketone with allyl bromide and commercial zinc dust in tetrahydrofuran. Excellent regioselectivity has been observed in the reaction of substituted allyl bromides.
Lewis Acid-Promoted Addition of Allyl(cyclopentadienyl)iron(II) Dicarbonyl To Unactivated Ketones
Jiang, Songchun,Turos, Edward
, p. 4639 - 4642 (2007/10/02)
The Lewis acid-promoted addition of allyl(cyclopentadienyl)iron(II) dicarbonyl (1) to unactivated ketones provides zwitterionic iron-olefin complexes 5 as isolable salts.Treatment of these complexes with NaI in wet acetone affords homoallylic alcohols in
