24582-52-3Relevant academic research and scientific papers
Synthesis and characterization of organoarsenic(III) derivatives with 2-aminocyclopentene 1-carbodithioc acid and with their nitrogen/sulfur alkyl derivatives
Rathore,Harkut,Nagar
, p. 2809 - 2820 (2007)
Phenylarsenic(III) Dimethoxide reacts with N-/S- alkyl of 2-aminocyclopentene 1- carbodithioic acid and its nitrogen-/sulfur-alkyl derivatives in 1:2 and 1:1 molar ratio yields some new complexes and addition complexes of the type: [image omitted] where R' = H,CH3,C2H5,C4H9 and R = CH3 and CH2N(C2H5). Reactants were mixed in 1:1 and 1:2 molar ratios and the resulting mixture was refluxed for 5 to 6 h to ensure completion of the reaction. Sodium chloride precipitated was filtered off. Yellow to dark brown colored solids were isolated; these complexes were found to be soluble in common organic solvents (e.g., CHCl3, etc.) These complexes and additional complexes have been characterized by physicochemical and spectroscopic studies. Copyright Taylor & Francis Group, LLC.
Synthesis and characterization of monophenylarsenic(III) derivatives of N-(alkyl)-2-mercaptoacetamides
Karra, R,Singh, Y P,Rai, A K
, p. 435 - 438 (2007/10/02)
N-(Alkyl)-2-mercaptoacetamide derivatives of monophenylarsenic(III) of the type PhAs(SCH2CONHR)Cl and PhAs(SCH2CONHR)2 (where R = C2H5, n-C3H7, n-C4H9, i-C4H9 and sec-C4H9) have been synthesized by the reactions of PhAsCl2 and the mercaptoacetamides in 1:1 and 1:2 molar ratios respectively.Their structural assignments have been made on the basis of elemental analysis, molecular weight determination and IR, 1H and 13C NMR spectral studies.
