24626-48-0

Upstream product

• 621-82-9 Cinnamic acid 
• 100-63-0 phenylhydrazine 
• 60-29-7 diethyl ether 
• 109572-62-5 cinnamoyl-methyl-malonic acid diethyl ester 
• 60299-77-6 cinnamoyl cyanide 
• 103-26-4 methyl cinnamate 
• 51589-22-1 N-phenylcinnamohydrazidoyl chloride 
• 112277-64-2 N-[(E)-1-Morpholin-4-yl-3-phenyl-prop-2-en-(Z)-ylidene]-N'-phenyl-hydrazine 
• 102-92-1 cinnamoyl chloride 
• 538-56-7 cinnamic acid anhydride 

Downstream Products

• 59161-33-0 cinnamic acid-(N',N'-diphenyl-hydrazide) 
• 112277-61-9 3-Phenyl-5-((E)-styryl)-3H-[1,3,4]thiadiazol-2-ylideneamine 
• 112277-65-3 3-Phenyl-5-((E)-styryl)-3H-[1,3,4]selenadiazol-2-ylideneamine 
• 112277-72-2 3-Phenyl-5-((E)-styryl)-3H-[1,3,4]thiadiazol-2-one 
• 112277-70-0 3-Phenyl-5-((E)-styryl)-3H-[1,3,4]selenadiazol-2-one 
• 112277-62-0 C₂₁H₁₈N₂O 
• 112277-71-1 C₁₆H₁₂N₄OS 
• 112277-69-7 C₁₆H₁₂N₄OSe 
• 112277-63-1 N-[3-Phenyl-5-((E)-styryl)-3H-[1,3,4]thiadiazol-(2Z)-ylidene]-acetamide 
• 112277-67-5 N-[3-Phenyl-5-((E)-styryl)-3H-[1,3,4]selenadiazol-(2Z)-ylidene]-acetamide 
• 112277-68-6 N-[3-Phenyl-5-((E)-styryl)-3H-[1,3,4]selenadiazol-(2Z)-ylidene]-benzamide 
• 112277-66-4 N-[3-Phenyl-5-((E)-styryl)-3H-[1,3,4]thiadiazol-(2Z)-ylidene]-benzamide 
• 94444-85-6 1,5-diphenyl-3-styryl-4-benzoylpyrazole 
• 94444-83-4 [2,4-Diphenyl-5-((E)-styryl)-2H-pyrazol-3-yl]-phenyl-methanone 

Relevant academic research and scientific papers

Methylaluminoxane (MAO)-assisted direct amidation of esters

Aliphatic and aromatic esters are efficiently transformed into amides in good to excellent yields, under mild conditions using methylaluminoxane (MAO). This reaction can be performed either at room temperature or by applying microwave irradiation.

Regioselectivity in Dipolar Cycloaddition Reactions of N-Phenylcinnamonitrilimine

The regioselectivity of the cycloadditions of α,β-unsaturated nitrilimine derived from N-phenylcinnamohydrazidoyl chloride 2 to C=Se, C=S and C=C doble bonds of the resonance stabilized selenocyanate and thiocyanate anions, enol tautomer of dibenzoylmethane and benzalacetophenone was investigated.The results indicate that the reactions studied are dipole-LUMO-dipolarophile-HOMO controlled and that the larger orbital coefficient in the LUMO of N-phenylcinnamonitrilimine is on the carbon atom bearing the styryl group.The structures of the cycloadducts were assigned and confirmed on the basis of their elemental analyses and spectra.