24764-93-0

Basic information

• Product Name: N,N’-(1,2-ethanediylidene)bis-hydroxyphenylamine
• Synonyms: N,N’-(1,2-ethanediylidene)bis-hydroxyphenylamine
• CAS NO: 24764-93-0
• Molecular Weight: 240.261
• Mol File: 24764-93-0.mol

Chemical Properties

• CAS DataBase Reference: N,N’-(1,2-ethanediylidene)bis-hydroxyphenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N’-(1,2-ethanediylidene)bis-hydroxyphenylamine(24764-93-0)
• EPA Substance Registry System: N,N’-(1,2-ethanediylidene)bis-hydroxyphenylamine(24764-93-0)

Safety Data

• Hazardous Substances Data: 24764-93-0(Hazardous Substances Data)

Upstream product

• 2206-27-1 dimethylsulfoxide-d6 
• 7647-14-5 sodium chloride 
• 131543-46-9 Glyoxal 
• 123-30-8 4-amino-phenol 

Downstream Products

• 218151-42-9 Rh(CO)(HOC₆H₄NCHCHNC₆H₄OH)(P(C₆H₅)3)2⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(HOC₆H₄NCHCHNC₆H₄OH)(P(C₆H₅)3)2]ClO₄ 
• 165395-89-1 [Rh2(COD)2Cl2](μ-glyoxalbis(4-hydroxy-anil)) 
• 165396-00-9 [Rh(norbornadiene)(glyoxalbis(4-hydroxy-anil))]BF₄ 
• 165395-94-8 RhCl(norbornadiene)(glyoxalbis(4-hydroxy-anil)) 
• 92417-77-1 Rh(CO)2(C₁₄H₁₂N₂O₂)⁽¹⁺⁾*RhCl₂(CO)2^(1-)=Rh₂Cl₂(CO)4(C₁₄H₁₂N₂O₂) 
• 131543-46-9 Glyoxal 
• 103-90-2 4-acetaminophenol 

Relevant articles and documents

Direct intramolecular carbon(sp2)-nitrogen(sp2) reductive elimination from gold(iii)

The reactivity of bidentate AuIII-Cl species, [(C^N)AuCl2], with a bisphosphine or carbon donor ligands results in reductive elimination. Combined experimental and computational investigations lead to the first evidence of a direct intramolecular C(sp2)-N(sp2) bond formation from a monomeric [(C^N)AuCl2] gold(iii) complex. We show that bidentate ligated Au(iii) systems bypass transmetallation to form C(sp2)-N(sp2) species and NHC-Au-Cl. Mechanistic investigations of the reported transformation reveal a ligand-induced reductive elimination via a key AuIII intermediate. Kinetic studies of the reaction support a second-order rate process.

α-Diimines as Versatile, Derivatizable Ligands in Ruthenium(II) p-Cymene Anticancer Complexes

α-Diimines are among the most robust and versatile ligands available in synthetic coordination chemistry, possessing finely tunable steric and electronic properties. A series of novel cationic ruthenium(II) p-cymene complexes bearing simple α-diimine liga

Water-Soluble, Disulfonated alpha-Diimine Rhodium(I) Complexes: Synthesis, Characterisation and Application as Catalyst Precursors in the Hydroformylation of 1-Octene

The synthesis and characterisation of two new water-soluble RhI mononuclear 1,4-diazabutadiene (DADs) complexes of general formula: [Rh(DADs-R)(COD)], where (DADs = sulfonated-tagged–1,4-diazabutadiene, COD = cy

Hydroformylation of olefins using redox-active rhodium(I) alpha-diimine-cored aryl ether metallodendrimers

Rhodium(I) poly(aryl ether)-based, core-functionalised alpha-diimine metallodendrimers were investigated as catalyst precursors in the rhodium-catalysed hydroformylation of terminal olefins, 1-octene and styrene. The electronic environment across the meta

N-Heterocyclic Carbene Catalyzed Deuteration of Aldehydes in D 2 O

An N-heterocyclic carbene (NHC)-catalyzed direct deuteration of aldehydes in a mixed solvent of deuterium oxide (D 2 O) and cyclopentyl methyl ether was established. The present deuteration is possibly initiated by the formation of a Breslow intermediate from the aldehyde and the NHC, with subsequent trapping by D 2 O providing the monodeuterated aldehyde.

α-Diimine homologues of cisplatin: synthesis, speciation in DMSO/water and cytotoxicity

The Pt(ii) α-diimine complexes [PtCl2{κ2N-(HCNR)2}] (R = C6H11, 1; 4-C6H10OH, 2; 4-C6H4CH3, 3; 4-C6H4OH, 4) and [PtCl2