24807-96-3

Basic information

• Product Name: 1,2-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE 3-ACETATE
• Synonyms: 1,2-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE 3-ACETATE;3-O-ACETYL-1,2-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE;3-O-ACETYL-1,2-O-ISOPROPYLIDENE-ALPHA-D-GLUCOPYRANOSE;3-O-acetyl-1,2-O-isopropylidene-alpha-D-glucofura;3-O-Acetyl-1,2-O-isopropylidene-a-D-glucopyranose;3-O-ACETYL-1,2-0-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE;3-O-Acetyl-1,2-O-isopropylidene-α-D-glucofuranose ,98%;3-O-Acetyl-1,2-O-isopropylidene-α-D-glucofuranose
• CAS NO: 24807-96-3
• Molecular Formula: C₁₁H₁₈O₇
• Molecular Weight: 262.26
• Mol File: 24807-96-3.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 391.98 °C at 760 mmHg
• Flash Point: 148.45 °C
• Appearance: /
• Density: 1.356 g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.521
• CAS DataBase Reference: 1,2-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE 3-ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE 3-ACETATE(24807-96-3)
• EPA Substance Registry System: 1,2-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE 3-ACETATE(24807-96-3)

Safety Data

• Hazardous Substances Data: 24807-96-3(Hazardous Substances Data)

Usage

General Description

1,2-O-isopropylidene-alpha-D-glucofuranose 3-acetate is a chemical compound that is derived from the sugar glucose. It is a derivative of glucose in which the hydroxyl group at the third carbon is acetylated, and the hydroxyl group at the first and second carbons are protected with an isopropylidene group. This chemical is commonly used in organic and bioorganic synthesis as a protecting group for the hydroxyl groups of glucose. Additionally, it can also be used as a starting material for the synthesis of other carbohydrate derivatives and pharmaceutical compounds. It is a white crystalline solid with a variety of potential applications in the field of organic chemistry.

InChI:InChI=1/C11H18O7/c1-5(13)15-8-7(6(14)4-12)16-10-9(8)17-11(2,3)18-10/h6-10,12,14H,4H2,1-3H3/t6-,7-,8+,9-,10-/m1/s1

Upstream product

• 16713-80-7 3-O-acetyl-1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose 
• 67-56-1 methanol 
• 17225-57-9 3-O-acetyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hexo-5-enofuranose 
• 98032-70-3 Acetic acid (3aR,5R,6S,6aR)-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester 
• 582-52-5 1,2:5,6-diacetone-D-glucose 

Downstream Products

• 2592-44-1 3-O-acetyl-1,2-O-isopropylidene-5,6-O-di-toluene-p-sulphonyl-α-D-glucofuranose 
• 10470-80-1 1,2,3,4,6-penta-O-acetyl-5-thio-α,β-D-glucopyranose 
• 16505-91-2 (3R,4S,5S,6R)-6-(hydroxymethyl)tetrahydro-2H-thiopyran-2,3,4,5-tetraol 
• 102029-58-3 3-O-acetyl-6-O-benzoyl-1,2-O-isopropylidene-5-O-methylsulphonyl-α-D-glucofuranose 
• 68095-73-8 3,5-Di-O-acetyl-1,2-O-isopropyliden-6-O-trityl-α-D-glucofuranose 
• 139710-09-1 5-O-Acetyl-1,2-O-isopropylidene-3-O-methyl-6-O-triphenylmethyl-α-D-glucopyranose 
• 51213-03-7 (1R)-1-[(3aR,5R,6S,6aR)-6-methoxy-2,2-dimethylperhydrofuro[2,3-d][1,3]dioxol-5-yl]-2-(trityloxy)ethan-1-ol 
• 110089-65-1 O⁶-acetyl-O¹,O²-isopropylidene-O⁵-(toluene-4-sulfonyl)-α-D-glucofuranose 
• 28642-63-9 O³,O⁶-diacetyl-O⁵-benzoyl-O¹,O²-isopropylidene-α-D-glucofuranose 
• 4118-60-9 5,6-anhydro-1,2-O-isopropylidene-β-L-idofuranose 
• 16749-46-5 6-deoxy-1,2-O-isopropylidene-β-L-idofuranose 
• 136505-32-3 Acetic acid (3aR,5S,6S,6aR)-5-{(R)-1-(benzothiazol-2-ylsulfanyl)-2-[(4-methoxy-phenyl)-diphenyl-methoxy]-ethyl}-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester 
• 136505-23-2 Acetic acid (3aR,5S,6R,6aR)-5-{(R)-1-(benzothiazol-2-ylsulfanyl)-2-[(4-methoxy-phenyl)-diphenyl-methoxy]-ethyl}-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester 
• 136505-36-7 1-((2R,3R,4R,5R)-4-Azido-3-hydroxy-5-{2-[(4-methoxy-phenyl)-diphenyl-methoxy]-ethyl}-tetrahydro-furan-2-yl)-5-methyl-1H-pyrimidine-2,4-dione 

Relevant articles and documents

A mild and efficient method for the chemoselective deprotection of acetonides with lanthanum(III) nitrate hexahydrate

Acetonides are hydrolyzed selectively and efficiently with lanthanum(III) nitrate hexahydrate in acetonitrile. The method has good compatibility with other sensitive hydroxyl protecting groups such as trityl, TBDMS, THP, OAc, OBz and OBn.

Lithium tetrafluoroborate: A mild and efficient reagent for the cleavage of dimethoxytrityl ethers

A mild and efficient method for the cleavage of dimethoxytrityl ethers using lithium tetrafluoroborate is reported.

Anthracyclinones, Part 4. The Use of DBN or DBU in a Novel Extension of the Marschalk Reaction leading to Hydroxyglycitylanthraquinones

Leuco-quinizarin (1) with propanal, 3-O-(p-chlorobenzyl)-(or 3-O-acetyl)-1,2-O-isopropylidene-α-D-xylo-pentodialdo-1,4-furanose (6a) or (6c), or 3-O-acetyl-3-C-ethynyl-1,2-O-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose (6b) in dimethylformamide soluti