24891-96-1Relevant academic research and scientific papers
Similarities and differences in the structures of 5-bromo-6-hydroxy-7,8- dimethylchroman-2-one and 6-hydroxy-7,8-dimethyl-5-nitrochroman-2-one
Goswami, Shailesh K.,Hanton, Lyall R.,McAdam, C. John,Moratti, Stephen C.,Simpson, Jim
, p. 407 - 411 (2013)
The title compounds, C11H11BrO3, (I), and C11H11NO5, (II), respectively, are derivatives of 6-hydroxy-5,7,8-trimethylchroman-2-one substituted at the 5-position by a Br atom in (I) and by a
The dichotomy between nitration of substituted 1,4-dimethoxybenzenes and formation of corresponding 1,4-benzoquinones by using nitric and sulfuric acid
Waterlot,Haskiak,Couturier
, p. 106 - 107 (2007/10/03)
Various alkyl-substituted p-dimethoxybenzenes (ArH) react readily With nitric acid and sulfuric to form nitroproducts (ARNO2). When the nitric acid is used in excess, the nitro-product react via either nitration to dinitrocompound (Ar(NO2)2) or via oxidative demethylation to nitro-p- quinone (Q). As such, the competition between the nitration, polynitration and oxidative dealkylation is effectively modulated by the added nitric acid and the alkyl-substituted p-dimethoxybenzenes.
