24962-55-8

Basic information

• Product Name: 4-IODOPHENYL 4-METHYLPHENYLSULFONATE
• Synonyms: 4-IODOPHENYL 4-METHYLPHENYLSULFONATE;P-IODOPHENYL P-TOLYLSULFONATE
• CAS NO: 24962-55-8
• Molecular Formula: C₁₃H₁₁IO₃S
• Molecular Weight: 374.19
• Mol File: 24962-55-8.mol
• Article Data: 4

Chemical Properties

• Melting Point: 99 °C
• Boiling Point: 445.6 ºC at 760 mmHg
• Flash Point: 223.3ºC
• Appearance: /
• Density: 1.689 g/cm3
• Vapor Pressure: 1.02E-07mmHg at 25°C
• Refractive Index: 1.637
• CAS DataBase Reference: 4-IODOPHENYL 4-METHYLPHENYLSULFONATE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-IODOPHENYL 4-METHYLPHENYLSULFONATE(24962-55-8)
• EPA Substance Registry System: 4-IODOPHENYL 4-METHYLPHENYLSULFONATE(24962-55-8)

Safety Data

• Hazardous Substances Data: 24962-55-8(Hazardous Substances Data)

Usage

General Description

4-IODOPHENYL 4-METHYLPHENYLSULFONATE is a chemical compound consisting of a phenyl ring with an iodine atom and a methylphenylsulfonate group attached to it. It is commonly used in organic synthesis as a reagent for the preparation of various aromatic compounds. 4-IODOPHENYL 4-METHYLPHENYLSULFONATE is often employed as a reactant in the synthesis of pharmaceuticals, agrochemicals, and other fine chemicals. It is known for its ability to facilitate carbon-carbon bond formation and is utilized in the development of new materials and chemical processes. Additionally, 4-IODOPHENYL 4-METHYLPHENYLSULFONATE has potential applications in the field of material science, making it a versatile and valuable chemical in various industrial and research settings.

InChI:InChI=1/C13H11IO3S/c1-10-2-8-13(9-3-10)18(15,16)17-12-6-4-11(14)5-7-12/h2-9H,1H3

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 1073-72-9 4-hydroxythioanisole 
• 540-38-5 p-Iodophenol 
• 455-16-3 p-toluenesulfonyl fluoride 
• 824-79-3 sodium 4-methylbenzenesulfinate 

Downstream Products

• 80459-48-9 4-tosyloxybenzaldehyde 
• 51804-15-0 4-carboxyphenyl 4-methylbenzenesulfonate 
• 131086-39-0 4-benzoylphenyl 4-methylbenzenesulfonate 
• 696-62-8 para-iodoanisole 
• 356031-48-6 4′-methoxy-[1,1′-biphenyl]-4-yl 4-methylbenzenesulfonate 
• 1433269-81-8 4-(2-phenylallyl)phenyl 4-methylbenzenesulfonate 
• 1160484-32-1 4-benzylphenyl tosylate 
• 101110-81-0 (E)-3-(4-(tosyloxy)phenyl)prop-2-enoic acid 
• 3001-15-8 4,4'-diiodobiphenyl 
• 133740-27-9 (2,4-dimethoxyphenyl)((2S,3S,3aS,4S,9bR)-7-methoxy-2,4-bis(4-methoxyphenyl)-2,3,3a,9b-tetrahydro-4H-furo[3,2-c]chromen-3-yl)methanone 

Relevant articles and documents

Electrochemical cross-coupling reactions of sodium arenesulfinates with thiophenols and phenols

A green electrochemical oxidative cross-coupling protocol for the generation of thiosulfonates and sulfonate esters using sodium arenesulfinates and thiophenols/phenols is disclosed. The protocol involves using inorganic and non-toxic NaI as both redox catalyst and supporting electrolyte at room temperature without oxidant and base. The reactions provide good yields of products and tolerate broad substrate scope. The mechanistic studies revealed that the reactions proceed via a radical pathway for the formation of SO2–S and SO2–O bonds.

Pd-Catalyzed Conversion of Aryl Iodides to Sulfonyl Fluorides Using SO2 Surrogate DABSO and Selectfluor

A one-pot Pd-catalyzed conversion of aryl iodide to aryl sulfonyl fluorides using DABSO and Selectfluor has been developed generating aryl sulfonyl fluorides in good to excellent yields. The reaction results in the generation of electronically and sterically diverse sulfonyl fluorides. Additionally, sulfonyl fluorides can be converted to aryl sulfonamides and sulfonic esters using Cs2CO3 under mild conditions.