25041-50-3

Basic information

• Product Name: Benzene, 1,1'-(1,1-dimethoxy-1,2-ethanediyl)bis-
• CAS NO: 25041-50-3
• Molecular Formula: C16H18O2
• Molecular Weight: 242.318
• Mol File: 25041-50-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1,1-dimethoxy-1,2-ethanediyl)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1,1-dimethoxy-1,2-ethanediyl)bis-(25041-50-3)
• EPA Substance Registry System: Benzene, 1,1'-(1,1-dimethoxy-1,2-ethanediyl)bis-(25041-50-3)

Safety Data

• Hazardous Substances Data: 25041-50-3(Hazardous Substances Data)

Upstream product

• 4369-00-0 (2,2,2-trimethoxyethyl)benzene 
• 100-52-7 benzaldehyde 
• 451-40-1 phenyl benzyl ketone 
• 149-73-5 trimethyl orthoformate 
• 21069-29-4 1-nitro-1-phenyl-2-ethanol 
• 622-42-4 1-nitro-1-phenylmethane 
• 67-56-1 methanol 
• 5468-44-0 α-nitrostyrene 
• 71-43-2 benzene 
• 501-65-5 diphenyl acetylene 
• 113675-06-2 1-methoxy-1,1-diphenyl-2-phenylseleninylethane 
• 113675-09-5 1-methoxy-1,1-diphenyl-2-phenylselenonylethane 
• 98329-52-3 1,1-diphenyl-1-methoxy-2-phenylselenenyl ethane 

Downstream Products

• 2154-56-5 benzyl radical 
• 38092-03-4 α,α-dimethoxybenzyl cation 
• 451-40-1 phenyl benzyl ketone 

Relevant articles and documents

Conjugate addition of acetal-derived benzyl radicals generated from low-valent titanium-mediated CO bond cleavage

A new method for the generation of benzyl radicals from acetals via low-valent titanium-mediated homolytic CO bond cleavage is presented. The low cost and availability of the developed titanium reagent enable efficient access to α-alkoxy carbon radical species via the developed reaction.

Reactions of O,O-Diprotonated Nitro Olefins with Benzenes. Formations of Phenylacetones, 4H-1,2-Benzoxazines and Biarylacetone Oximes

O,O-Diprotonated nitro olefins undergo three alternative electrophilic reactions which yield α-phenylacetones, 4H-1,2-benzoxazines and biphenylacetone oximes depending on the reaction conditions (temperature and time) and aromatic substrates.Although these reactions are seemingly divergent, a common intermediate of a phenylated protonated aci-nitro species, derived from the dication, is postulated to be involved in the reactions.Furthermore, the formation of benzoxazines and biphenylacetone oximes can be interpreted in terms of participation of novel chemical species with phenylethylene dication character derived from the common intermediate.

Metalation of Alkynes. Part 2. Behaviour of Alkynes with Mercury(II)Acetate in Methanol: a Systematic Reinvestigation

The reaction of a series of alkynes with mercury(II)acetate, both in equimolar and catalytic amounts, were investigated in methanol.Hex-1-yne, oct-1-yne, oct-4-yne, 1,4-diacetoxybut-2-yne, methyl oct-2-ynoate, methyl 3-phenylpropynoate, oct-2-ynoic acid, phenylpropynoic acid, oct-1-yn-3-ol, 1-ethynylcyclohexanol, 1-ethynylcyclohexamine, phenylethyne, diphenylethyne, and ethynylferrocene were the examined substrates.The non-mercuriated products from the reaction were the corresponding vinyl ether, dialkoxyalkane, and ketone, isolated under preparative conditions.The presence of 0.1percent toluene-p-sulphonic acid increased the reactivity.The reactions of oct-1-yne and oct-4-yne were studied in detail by following with time the formation of the products under a variety of conditions, and a mechanistic scheme was drawn.For comparison, styrene, trans-oct-4-ene, and trans-β-methylstyrene were treated with 5 molpercent mercury(II) acetate.The reaction of alkenes was found to be non-catalytic.