25062-93-5Relevant articles and documents
2-Bromoethyl glycosides for synthesis of glycoconjugates on solid support
Ellervik, Ulf,Jacobsson, M?rten,Ohlsson, J?rgen
, p. 2421 - 2429 (2007/10/03)
2-Bromoethyl glycosides can easily and in high yields be transformed into sulfones by treatment with a suitable thiol followed by oxidation with mCPBA. The observation that the so formed sulfones were cleaved by treatment with NaOMe/MeOH was used to desig
Reactivity in Z-Philic Displacements in α-Halogenosulfones
Vernon, Adam,Stirling, Charles J. M.
, p. 1609 - 1610 (2007/10/02)
Rates of Z-philic reactions in β-substituted α-bromosulfones have been measured; for displacement-protonation ρ* = 2.9, and isotope fractionation factors close to 2.4 demonstrate extensive C-protonation in the transition structure.