25076-84-0

Basic information

• Product Name: 1-(N-Methyl-N-phenylamino)-2-methyl-1-propene
• Synonyms: 1-(N-Methyl-N-phenylamino)-2-methyl-1-propene
• CAS NO: 25076-84-0
• Molecular Weight: 161.247
• Mol File: 25076-84-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(N-Methyl-N-phenylamino)-2-methyl-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(N-Methyl-N-phenylamino)-2-methyl-1-propene(25076-84-0)
• EPA Substance Registry System: 1-(N-Methyl-N-phenylamino)-2-methyl-1-propene(25076-84-0)

Safety Data

• Hazardous Substances Data: 25076-84-0(Hazardous Substances Data)

Upstream product

• 78-84-2 isobutyraldehyde 
• 100-61-8 N-methylaniline 
• 76527-75-8 <(methylphenylamino)methyl>diphenylphosphine oxide 
• 122-98-5 2-Anilinoethanol 
• 51439-16-8 2-Isopropyl-3-phenyl-1,3-oxazolidine 

Downstream Products

• 2769-43-9 3,3-dimethyl-4-(N-methylanilino)-1-phenylazetidin-2-one 
• 1235304-85-4 C₁₂H₁₀NO₄S₂^(1-)*C₁₆H₂₀FN₂⁽¹⁺⁾ 
• 1235304-69-4 3-fluoro-3-methyl-2-[methyl(phenyl)amino]butanenitrile 
• 88017-51-0 3-methyl-2-[methyl(phenyl)amino]butanenitrile 
• 1169620-16-9 N-methyl-N-(1,1,1-trifluoro-3-methylbutan-2-yl)aniline 
• 100-61-8 N-methylaniline 
• 136463-77-9 2,2-Dimethyl-3-(methyl-phenyl-amino)-3-methylsulfanyl-N-phenyl-propionamide 
• 78-84-2 isobutyraldehyde 
• 5782-58-1 1-Methylanilino-4-methyl-1-penten-3-on 

Relevant articles and documents

Formation of azomethine ylids by thermolysis of oxazolidines. Study of the reaction in solution and in the gaseous phase

Thermolysis of oxazolidines leads to azomethine ylids via cycloreversion.In the liquid phase, these intermediates then give 1-3 dipolar cycloaddition; in the gaseous phase, they lead to aziridines.With an alkyl group in position 2, we observed also the formation of enamines.The effect of substituents on both the cycloreversion reaction and the evolution of azomethine ylids was studied.The mechanism of the process tautomerism aziridine -> azomethine ylid -> enamine is discussed.Keywords - azomethine ylids / oxazolidines / cycloreversion / aziridines / enamines / tautomerism

Enamine synthesis using the Horner-Wittig reaction. Part 1. (Aminomethyl)diphenylphosphine oxides, new formyl anion equivalents

Using the Horner-Wittig reagent (morpholinomethyl)diphenylphosphine oxide (7), aromatic, aliphatic and α,β-unsaturated aldehydes are converted into morpholino enamines of their homologous aldehydes.With diphenylphosphine oxide (12), the same aldehydes, together with the ketones (cyclic as well as acyclic, both saturated and α,β-unsaturated), are converted into enamines of their homologous aldehydes.Both types of enamines are converted into the corresponding aldehydes by mild, acid-catalyzed hydrolysis, showing the utility of 7 and 12, as formyl anion equivalents.Preparation of each geometrical isomer of the N-methylanilino enamines is possible since the intermediate diastereoisomeric adducts 13 can be separated.