2516-75-8Relevant articles and documents
Rhodium-catalyzed carbonylative synthesis of silyl-substituted indenones
Zhu, Fengxiang,Spannenberg, Anke,Wu, Xiao-Feng
supporting information, p. 13149 - 13152 (2017/12/26)
A novel and efficient rhodium-catalyzed procedure for the preparation of silyl-substituted indenones has been developed. Using silanes and internal alkynes as the substrates, in the presence of CO, good to excellent yields of the desired indenones were isolated. A wide range of functional groups, encompassing esters, amines, nitriles and halides, is compatible in this system.
Electrochemical method for the production of organofunctional silanes
-
Page/Page column 3, (2008/06/13)
Organofunctional silanes are prepared in high yield by electrochemically reacting a silane bearing a halo or alkoxy group with a hydrocarbon bearing a halo or alkoxy group in an undivided electrolysis cell with no or minimal complexing agent present.