25246-83-7

Basic information

• Product Name: Cyclohexane, (1,1-dimethylethoxy)-
• Synonyms: tert-butoxycyclohexane;Cyclohexane,(1,1-dimethylethoxy);O-TERT-BUTYL CYCLOHEXANOL;cyclohexyl tert-butyl ether;t-butoxycyclohexane;tert-butyl-cyclohexyl ether;tert-Butyl-cyclohexyl-aether;cyclohexyl t-butyl ether
• CAS NO: 25246-83-7
• Molecular Formula: C10H20O
• Molecular Weight: 156.268
• Mol File: 25246-83-7.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 208 °C
• Density: 0.902 g/cm3
• CAS DataBase Reference: Cyclohexane, (1,1-dimethylethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, (1,1-dimethylethoxy)-(25246-83-7)
• EPA Substance Registry System: Cyclohexane, (1,1-dimethylethoxy)-(25246-83-7)

Safety Data

• Hazardous Substances Data: 25246-83-7(Hazardous Substances Data)

Upstream product

• 75-65-0 tert-butyl alcohol 
• 108-93-0 cyclohexanol 
• 110-05-4 di-tert-butyl peroxide 
• 110-82-7 cyclohexane 
• 1634-04-4 tert-butyl methyl ether 
• 24424-99-5 di-tert-butyl dicarbonate 
• 540-88-5 acetic acid tert-butyl ester 
• 110-83-8 cyclohexene 
• 614-45-9 tert-Butyl peroxybenzoate 
• 931-50-0 cyclohexylmagnesium bromide 
• 115-11-7 isobutene 
• 931-51-1 cyclohexylmagnesiumchloride 

Downstream Products

• 108-93-0 cyclohexanol 
• 2108-66-9 cyclohexyl nitrate 

Relevant articles and documents

Skeletal Rearrangement for Water Loss from Molecular Protonated Ions of t-Butoxycyclohexane

Isotopic labelling and chemical substitution support the proposition that the skeletal rearrangement for water loss from molecular protonated ions of t-butoxycyclohexane involves competition between three reaction pathways.The principal reaction pathway (83percent) involves migration of the t-butyl group to the 2-(6-) position of the cyclohexyl ring with reciprocal hydrogen transfer.A second reaction pathway (12percent) involves ring contraction followed by reciprocal exchange of the t-butyl group with the 2-(5-) hydrogen atom of the nascent cyclopentyl ring.The third reaction pathway (5percent) involves rearrangement of a proton-bound complex to permit ipso attack by isobutene.Stereospecific substitutions indicate that the principal reaction pathway is susceptible to 1,3-diaxial interactions.

METHOD FOR PRODUCING ASYMMETRIC ALKYL ETHER HAVING TERTIARY ALKYL GROUP

PROBLEM TO BE SOLVED: To provide a method capable of obtaining an asymmetric alkyl ether having a tertiary alkyl group easily and industrially. SOLUTION: (1) There is provided a method for producing an asymmetric alkyl ether having a tertiary alkyl group by subjecting a tertiary alcohol and a primary alcohol or a secondary alcohol to a dehydration reaction using activated clay as a catalyst. (2) There is provided the method for producing an asymmetric alkyl ether having a tertiary alkyl group according to (1), where the tertiary alcohol is any one selected from the group consisting of tert-butanol, tert-amylalcohol and 1-adamantyl alcohol. SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT

CATALYTIC C-H BOND ACTIVATION FOR THE SYNTHESIS OF ETHERS AND THIOETHERS

Disclosed is a method for the transition metal-mediated oxidation of C-H bonds to form C-0 or C-S bonds. The methods are useful for the formation of ethers (R-OR') from alcohols, R'OH, and sp3 -hybridized C-H bonds in substrates, R-H. Aryl or heteroaryl acetates may also be used for C-H to C-OAr bond formation. The methods are also useful in the preparation of C-S bonds from acetyl-protected thiols, MeC(0)SR, and disulfides, RSSR. Advantageously, the methods minimize reaction steps, the handling of oxidized intermediates, and environmental impact.