25346-05-8

Basic information

• Product Name: N,N-dinitromethanamine
• Synonyms: methanamine, N,N-dinitro-; N,N-Dinitromethanamine
• CAS NO: 25346-05-8
• Molecular Formula: CH₃N₃O₄
• Molecular Weight: 121.0522
• Mol File: 25346-05-8.mol

Chemical Properties

• Boiling Point: 238.5°C at 760 mmHg
• Flash Point: 98.1°C
• Density: 1.554g/cm³
• Vapor Pressure: 0.0422mmHg at 25°C
• Refractive Index: 1.488
• CAS DataBase Reference: N,N-dinitromethanamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dinitromethanamine(25346-05-8)
• EPA Substance Registry System: N,N-dinitromethanamine(25346-05-8)

Safety Data

• Hazardous Substances Data: 25346-05-8(Hazardous Substances Data)

Upstream product

• 63745-44-8 N-nitro-N-butylacetamide 
• 74-88-4 methyl iodide 
• 186581-53-3 diazomethane 
• 624-83-9 methyl isocyanate 
• 63745-45-9 N-Methyl-N-nitroisovaleriansaeureamid 
• 14442-60-5 N-methyl-N-nitroacetamide 
• 63745-46-0 N-Methyl-N-nitrotrimethylacetamid 
• 63745-42-6 N-Methyl-N-nitrobuttersaeureamid 
• 59476-45-8 N-Propionyl-N-methyl-nitramin 
• 79-16-3 N-methyl-acetamide 
• 67135-94-8 methyl-nitro-amine; tetramethylammonium salt 
• 598-57-2 methylnitroamine 

Downstream Products

• 3760-55-2 N-nitropyrrolidine 
• 4164-30-1 diisopropylnitramine 
• 75-52-5 nitromethane 
• 624-91-9 methyl nitrite 
• 598-58-3 methyl nitrate 
• 67-56-1 methanol 
• 51625-40-2 2,4,6-Trinitro-N-3',3',3'-trinitropropylphenylnitramin 
• 86578-95-2 3,3-dinitrobutyl-N-nitroamine 
• 479-45-8 tetryl 
• 30893-21-1 N,N-diisobutylnitramine 
• 42499-41-2 1-Nitro-piperazin 

Relevant articles and documents

A new synthesis of alkyl-N,N-dinitramines by direct nitration of isocyanates

A facile conversion of aliphatic isocyanates to N,N-dinitramines has been developed. An aliphatic isocyanate is treated with a mixture of nitronium fluoroborate and nitric acid in acetonitrile giving fair yields and simplifying the existing synthesis.

Dinitramide and its salts 7. Alkylation of dinitramide and its salts

The dinitramide anion shows ambident properties.Its reactions with alkylating agents give rise to N- or O-alkylated products or their mixtures.The reactions of alkylated products with bases were studied. - Key words: dinitramide, dinitramide salts, N-alkyl-N,N-dinitroamines, N-alkoxy-N'-nitrodiazene N-oxides.

Dinitramide and its salts: 9. Mercury(II) dinitramidate, a new reagent in chemistry of organomercury compounds

The potentialities of synthesis on the basis of mercury(II) dinitramidate Hg(N3O4)2 in mercuration, addition to the double carbon-carbon bond, alkylation, and complexation are shown.

Dinitramide and its salts 1. Synthesis of dinitramide salts by decyanoethylation of N,N-dinitro-β-aminopropionitrile

A strategy of organic synthesis has been developed for a new class of inorganic compounds, viz., dinitramide and its metal, ammonium, and substituted ammonium salts.The basic concepts have been tested in model reactions of β-substituted derivatives of N-a

N-Nitration of amides. VIII. Kinetics and mechanism of the nitrolysis of N-nitro-N-alkylamides of carboxylic acids by nitronium tetrafluoroborate in an acetonitrile medium

The kinetics of the nitrolysis of N-nitro-N-alkylamides of two types R'C(O)N(NO2)CH3, where R'=CH3, C2H5, C3H7, iso-C4H9, C4H9, tert-C4H9, and CH3C(O)N(NO2)R, where R=C2H5, C3H7, C4H9 nitronium tetrafluoroborate in an acetonitrile medium with the formation of N,N-dinitroalkylamines were studied by a spectrophotometric method.The stage which determines the reaction rate is attack by the nitronium ion at the nitrogen atom of the amide.In the series of N-methylamides of carboxylic acids the effect of the substituent R' on the reactivity is due largely to its inductive effect.An isokinetic relationship was obtained for the reaction series; the isokinetic temperature amounts to 233 +/- 10 deg K.In the series of N-nitro-N-alkylacetamides a correlation is observed between the logarithms of the rate constants and the steric constants of the substituents ES0.The reaction series is isenthalpic.