25348-08-7Relevant articles and documents
Xilobam: Analysis, determination of decomposition products, and assessment of stability
Janicki,Walkling,Erlich,Bainbridge
, p. 778 - 780 (1981)
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Synthesis of Urea Derivatives from CO2 and Silylamines
Xu, Maotong,Jupp, Andrew R.,Ong, Maegan S. E.,Burton, Katherine I.,Chitnis, Saurabh S.,Stephan, Douglas W.
supporting information, p. 5707 - 5711 (2019/04/16)
A series of thirty-three N,N′-diaryl, dialkyl, and alkyl-aryl ureas have been prepared in pyridine or toluene by reaction of silylamines with CO2. This protocol is shown to provide facile access to 13C-labeled ureas, as well as chiral and macrocyclic ureas. These reactions proceed through initial generation of the corresponding silylcarbamates, which subsequently react with silylamine under thermal conditions to afford the thermodynamically favored urea and disilyl ether.
N-heterocyclic carbene - Palladium complexes as efficient catalysts for the oxidative carbonylation of amines to ureas
Zheng, Shuzhan,Peng, Xingao,Liu, Jianming,Sun, Wei,Xia, Chungu
, p. 1471 - 1476 (2008/02/09)
A highly efficient oxidative carbonylation reaction of amines to ureas was developed making use of carbene-palladium complexes in the absence of any promoter. Both aliphatic amines and aromatic amines were transformed in good to excellent yields to the expected ureas.