25354-46-5

Basic information

• Product Name: Benzene, 1,1',1''-(1-bromo-1-ethenyl-2-ylidene)tris[4-methoxy-
• CAS NO: 25354-46-5
• Molecular Formula: C23H21BrO3
• Molecular Weight: 425.322
• Mol File: 25354-46-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1',1''-(1-bromo-1-ethenyl-2-ylidene)tris[4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1',1''-(1-bromo-1-ethenyl-2-ylidene)tris[4-methoxy-(25354-46-5)
• EPA Substance Registry System: Benzene, 1,1',1''-(1-bromo-1-ethenyl-2-ylidene)tris[4-methoxy-(25354-46-5)

Safety Data

• Hazardous Substances Data: 25354-46-5(Hazardous Substances Data)

Upstream product

• 696-62-8 para-iodoanisole 
• 104-01-8 4-Methoxyphenylacetic acid 
• 14062-18-1 ethyl p-methoxyphenylacetate 
• 56-23-5 tetrachloromethane 
• 7109-27-5 1,1,2-tris(4-methoxyphenyl)ethene 
• 7726-95-6 bromine 
• 1817-87-4 1,1,2-tris-(4-methoxy-phenyl)-ethanol 

Downstream Products

• 83248-38-8 1-(acetylamino)-1,2,2-tris(p-methoxyphenyl)ethene 
• 93472-43-6 7-Methoxy-3,4-bis-(4-methoxy-phenyl)-1-methyl-isoquinoline 
• 90-96-0 bis(p-methoxyphenyl)methanone 
• 569-57-3 chlorotrianisene 
• 96784-47-3 1-Acetoxy-1,2,2-tris(4-methoxyphenyl)ethene 
• 133627-96-0 9-bromo-3,6-dimethoxy-10-(p-methoxyphenyl)phenanthrene 
• 41299-01-8 1,2,2-trianisyl ethanol 
• 5159-85-3 Tris-(4-methoxy-phenyl)-acrylsaeure-butylester 
• 5159-87-5 Tris-(4-methoxy-phenyl)-acrylsaeure-propylester 
• 5159-86-4 methyl tri-(4-methoxyphenyl)acrylate 
• 97432-74-1 6-Methoxy-2,3-bis-(4-methoxy-phenyl)-1-benzyliden-inden 
• 95821-83-3 2,3,3-Tris-(4-methoxy-phenyl)-propyl-formiat 
• 96762-89-9 2,3,3-Tris-(4-methoxy-phenyl)-propyl-acetat 
• 95622-12-1 2,3,3-tris(4-methoxyphenyl)propan-1-ol 

Relevant articles and documents

Electrochemical Fluorination of Vinyl Boronates through Donor-Stabilized Vinyl Carbocation Intermediates**

The electrochemical generation of vinyl carbocations from alkenyl boronic esters and boronates is reported. Using easy-to-handle nucleophilic fluoride reagents, these intermediates are trapped to form fully substituted vinyl fluorides. Mechanistic studies support the formation of dicoordinated carbocations through sequential single-electron oxidation events. Notably, this electrochemical fluorination features fast reaction times and Lewis acid-free conditions. This transformation provides a complementary method to access vinyl fluorides with simple fluoride salts such as TBAF.