25368-56-3

Basic information

• Product Name: 9-Hydroxy-2-nonanone
• Synonyms: 9-Hydroxy-2-nonanone
• CAS NO: 25368-56-3
• Molecular Formula: C₉H₁₈O₂
• Molecular Weight: 158.24
• Mol File: 25368-56-3.mol
• Article Data: 13

Chemical Properties

• Melting Point: 23-23.5 °C
• Boiling Point: 268.9±23.0 °C(Predicted)
• Appearance: /
• Density: 0.921±0.06 g/cm3(Predicted)
• PKA: 15.19±0.10(Predicted)
• CAS DataBase Reference: 9-Hydroxy-2-nonanone(CAS DataBase Reference)
• NIST Chemistry Reference: 9-Hydroxy-2-nonanone(25368-56-3)
• EPA Substance Registry System: 9-Hydroxy-2-nonanone(25368-56-3)

Safety Data

• Hazardous Substances Data: 25368-56-3(Hazardous Substances Data)

Upstream product

• 61720-56-7 8-oxo-1-nonanal 
• 201230-82-2 carbon monoxide 
• 40980-02-7 (E)-8-oxo-non-2-enoic acid 
• 1339804-13-5 C₁₂H₂₂O₄ 
• 821-41-0 5-Hexen-1-ol 
• 67-64-1 acetone 
• 4450-40-2 7-cyanoheptanoic acid ethyl ester 
• 855654-88-5 (5-cyano-pentyl)-malonic acid diethyl ester 
• 6621-59-6 6-bromo-1-hexanenitrile 
• 111-24-0 1,5-dibromo-pentane 
• 13038-21-6 non-8-en-1-ol 
• 10160-26-6 9-(2-tetrahydropyranyloxy)-1-nonyne 
• 1007476-32-5 sodium ethyl acetylacetate enolate 
• 22054-07-5 8-hydroxyoctanenitrile 

Downstream Products

• 13038-21-6 non-8-en-1-ol 
• 5009-32-5 non-8-en-2-one 
• 63768-13-8 non-7-en-1-ol 
• 5222-62-8 cis-1-acetyl-2-methylcyclohexane 
• 5222-61-7 (+/-)-1-(trans-2-methyl-cyclohexyl)-ethanone 
• 1339804-12-4 7-(3-methyl-3H-diazirin-3-yl)heptyl 4-methylbenzenesulfonate 

Relevant articles and documents

Selective enclathration of linear alkanols by a self-assembled coordination cage. Application to the catalytic wacker oxidation of ω-alkenols

Linear alkanols were efficiently enclathrated by a self-assembled cage (1) to give a 1:2 host-guest complex as confirmed by NMR and crystallographic analyses. Cage 1 also enclathrated an ω-alkenol, 8-nonen-1-ol, and, upon heating, Wacker-type oxidation took place with a catalytic amount of 1 to give 9-hydroxynonan-2-one in a good yield. Copyright

ALDEHYDE-SELECTIVE WACKER-TYPE OXIDATION OF UNBIASED ALKENES

This disclosure is directed to methods of preparing organic aldehydes, each method comprising contacting a terminal olefin with an oxidizing mixture comprising: (a) a dichloro-palladium complex; (b) a copper complex; (c) a source of nitrite; under aerobic reaction conditions sufficient to convert at least a portion of the terminal olefin to an aldehyde.

Tandem decarboxylative hydroformylation-hydrogenation reaction of α,β-unsaturated carboxylic acids toward aliphatic alcohols under mild conditions employing a supramolecular catalyst system

A new atom economic catalytic method for a highly chemoselective reduction of α,β-unsaturated carboxylic acids to the corresponding saturated alcohols under mild reaction conditions, compatible with a wide range reactive functional groups, is reported. The new methodology consists of a novel tandem decarboxylative hydroformylation/aldehyde reduction sequence employing a unique supramolecular catalyst system.