2540-99-0

Basic information

• Product Name: 3,3',4,4'-DIPHENYLSULFONETETRACARBOXYLIC DIANHYDRIDE
• Synonyms: 3,3',4,4'-DIPHENYLSULFONETETRACARBOXYLIC DIANHYDRIDE;4,4'-SULFONYLDIPHTHALIC ANHYDRIDE;DSDA;4,4'-Sulfonyldiphthalic dianhydride;diphenylsulfonetetracarboxylicdianhydride;3,3,4,4''-DIPHENYLSULFONETETRACARBOXYLIC DIANHYDRIDE 96+%;4,4'-Sulfonylbis(benzene-1,2-dicarboxylic acid)1,2:1',2'-dianhydride;4,4'-Sulfonylbisphthalic 1,2:1',2'-dianhydride
• CAS NO: 2540-99-0
• Molecular Formula: C₁₆H₆O₈S
• Molecular Weight: 358.28
• Product Categories: Aromatic Tetracarboxylic Dianhydrides (for High-Performance Polymer Research);Diphenyl Sulfones (for High-Performance Polymer Research);Functional Materials;Reagent for High-Performance Polymer Research
• Mol File: 2540-99-0.mol
• Article Data: 5

Chemical Properties

• Melting Point: 283 °C
• Boiling Point: 718.549 °C at 760 mmHg
• Flash Point: 388.364 °C
• Appearance: /
• Density: 1.756 g/cm³
• Vapor Pressure: 1.69E-20mmHg at 25°C
• Refractive Index: 1.697
• Storage Temp.: Inert atmosphere,Room Temperature
• CAS DataBase Reference: 3,3',4,4'-DIPHENYLSULFONETETRACARBOXYLIC DIANHYDRIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3',4,4'-DIPHENYLSULFONETETRACARBOXYLIC DIANHYDRIDE(2540-99-0)
• EPA Substance Registry System: 3,3',4,4'-DIPHENYLSULFONETETRACARBOXYLIC DIANHYDRIDE(2540-99-0)

Safety Data

• Hazardous Substances Data: 2540-99-0(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 2540-99-0 differently. You can refer to the following data:
1. 3,3',4,4'-Diphenylsulfonetetracarboxylic dianhydride is a novel class of human immunodeficiency virus type 1 integrase inhibitors.
2. 3,3'',4,4''-Diphenylsulfonetetracarboxylic dianhydride is a novel class of human immunodeficiency virus type 1 integrase inhibitors.

InChI:InChI=1/C16H6O8S/c17-13-9-3-1-7(5-11(9)15(19)23-13)25(21,22)8-2-4-10-12(6-8)16(20)24-14(10)18/h1-6H

Synthetic route

3,3’,4,4’-diphenylsulfonetetracarboxylic acid (10595-31-0) → 3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0)

Conditions	Yield
With 2,6-bis[(2,2,6,6-tetramethylpiperidin-1-yl)methyl]phenylboronic acid In propyl cyanide for 12h; Reflux;	92%

3,3′,4,4′-diphenylsulfidetetracarboxylic dianhydride (25884-43-9) → 3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0)

Conditions	Yield
With dipotassium peroxodisulfate; ammonium cerium (IV) nitrate; tetra-(n-butyl)ammonium iodide In water; acetonitrile at 60℃; Temperature; Solvent; Reagent/catalyst;

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + 1-amino-2-propene (107-11-9) → C22H16N2O6S

Conditions	Yield
With acetic acid at 20℃; for 9h; Inert atmosphere; Reflux;	92%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + LEUCINE (328-39-2) → C28H28N2O10S

Conditions	Yield
With acetic acid at 120℃;	90%

aluminum(III) nitrate nonahydrate + 3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) → [Al2(OH)2(DPSTC)(H2O)2]·0.5H2O

Conditions	Yield
With sodium hydroxide In water at 170℃; for 5h; Microwave irradiation;	85%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + (R)-leucine (328-38-1) → C28H28N2O10S

Conditions	Yield
With acetic acid at 120℃; for 0.166667h; Microwave irradiation;	79%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + gallium(III) nitrate heptahydrate + water (7732-18-5) → Ga-CAU-11-COOH

Conditions	Yield
With acetic acid; sodium hydroxide at 180℃; for 24h; Autoclave;	77%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + L-leucine (61-90-5) → C28H28N2O10S

Conditions	Yield
With acetic acid at 120℃; for 0.166667h; Microwave irradiation;	72%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + recorcinol (108-46-3) → 2-(3,6,9-trihydroxyxanthen-9-yl)-5-(3,4-dicarboxyphenylsulfonyl)benzoic acid lactone

Conditions	Yield
at 180℃; for 6h;	66.5%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) → 3,3’,4,4’-diphenylsulfonetetracarboxylic acid (10595-31-0)

Conditions	Yield
With water Hydrolysis; Heating;	65%

4,4'-bipyridine (553-26-4) + 3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + water (7732-18-5) + silver nitrate → [Ag(4,4'-bipyridine)]2*3,3',4,4'-tetracarboxydiphenylsulfone(2-)*2water

Conditions	Yield
In water High Pressure; heating a mixt. of silver salt, ligand and bipyridine in water in autoclave at 120°C for 4 d, cooling to room temp. during 8 h; elem. anal.;	65%

1,10-Phenanthroline (66-71-7) + 3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + copper(II) nitrate trihydrate + water (7732-18-5) → [Cu4(3,3',4,4'-diphenylsulfonetetracarboxylic acid-2H)4(1,10-phenanthroline)4]*12H2O

Conditions	Yield
In water High Pressure; mixt. of Cu(NO3)2*3H2O (0.10 mmol), 3,3',4,4'-diphenylsulfonetetracarboxylic dianhydride (0.05 mmol), phenenthroline (0.05 mmol) and H2O stirred(20 min) in air; heated in autoclave (160°C, 72 h); cooled to room temp. (5°C/h); elem. anal.;	65%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + water (7732-18-5) + cobalt(II) diacetate tetrahydrate (6147-53-1) + trans-1,2-bis(4-pyridyl)ethylene (1135-32-6) → {[Co2(dstc)(bpe)2(H2O)2]·2H2O}n

Conditions	Yield
In water at 150℃; for 72h; Autoclave;	65%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + silver nitrate + trans-1,2-bis(4-pyridyl)ethylene (1135-32-6) → [Ag(bpe)2]·H3dstc

Conditions	Yield
In water at 120℃; for 72h; Autoclave;	55%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + Pyridine-2,3-dicarboxylic acid (89-00-9) + ammonium chloride (12125-02-9) + copper dichloride → C58H24Cu2N22O2S

Conditions	Yield
With ammonium dimolybdate; urea for 10h; Heating; Reflux;	54%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + 1,2-bis(4'-pyridyl)ethane (4916-57-8) + water (7732-18-5) + cobalt(II) diacetate tetrahydrate (6147-53-1) → {[Co2(dstc)(bpe)2(H2O)2]·2H2O}n

Conditions	Yield
In water at 150℃; for 72h; Autoclave;	52%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + glycine (56-40-6) → C20H12N2O10S

Conditions	Yield
In N,N-dimethyl-formamide at 100℃;	52%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + Pyridine-2,3-dicarboxylic acid (89-00-9) + ammonium chloride (12125-02-9) + nickel dichloride → C58H24N22Ni2O2S

Conditions	Yield
With ammonium dimolybdate; urea for 10h; Heating; Reflux;	51%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + 1,3-di(4-pyridyl)propane (17252-51-6) + water (7732-18-5) + silver nitrate → [Ag(bpe)2]·H3dstc

Conditions	Yield
In water at 130℃; for 72h; Autoclave;	50%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + aluminium(III) chloride hexahydrate → ([Al(OH)(H2DPSTC)]·0.5H2O)

Conditions	Yield
With sodium hydroxide In water at 170℃; for 5h; Microwave irradiation;	50%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + C13H15Cl2N3 → C42H32Cl4N6O6S

Conditions	Yield
In toluene for 13h; Reflux;	46%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + Pyridine-2,3-dicarboxylic acid (89-00-9) + ammonium chloride (12125-02-9) + iron(II) chloride → C58H24Fe2N22O2S

Conditions	Yield
With ammonium dimolybdate; urea for 10h; Heating; Reflux;	44%

4,4'-bipyridine (553-26-4) + 3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + water (7732-18-5) + cadmium(II) acetate dihydrate (5743-04-4) + sodium hydroxide (1310-73-2) → ([Cd5(3,3',4,4'-diphenylsulfonetetracarboxylic acid-4H)2(4,4'-bipyridine)2(μ3-OH)2(H2O)4]*4H2O)n

Conditions	Yield
In water High Pressure; mixt. of Cd(CH3COO)2*2H2O (0.1 mmol), 3,3',4,4'-diphenylsulfonetetracarboxylic dianhydride (0.05 mmol), 4,4'-bipyridine (0.05 mmol), NaOH (0.2 mmol) and H2O stirred (20 min) in air; heated in autoclave (160°C,72 h); cooled to room temp. (5°C/h); elem. anal.;	43%

4,4'-bipyridine (553-26-4) + 3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + copper(II) nitrate trihydrate + water (7732-18-5) + sodium hydroxide (1310-73-2) → [Cu3(3,3',4,4'-diphenylsulfonetetracarboxylic acid-4H)(4,4'-bipyridine)(μ2-OH)2(H2O)2]n

Conditions	Yield
In water High Pressure; mixt. of Cu(NO3)2*3H2O (0.10 mmol), 3,3',4,4'-diphenylsulfonetetracarboxylic dianhydride (0.05 mmol), 4,4'-bipyridine (0.05 mmol), NaOH (0.2 mmol) and H2O stirred (20 min) in air; heated in autoclave (160°C, 72 h); cooled to room temp. (5°C/h); elem. anal.;	40%

1,10-Phenanthroline (66-71-7) + 3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + cadmium(II) acetate trihydrate + hydrazine hydrate (7803-57-8) → C16H8N4O6S(2-)*C12H8N2*2H2O*Cd(2+)

Conditions	Yield
In water at 170℃; for 96h; pH=8;	40%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + copper(II) nitrate trihydrate + water (7732-18-5) + trans-1,2-bis(4-pyridyl)ethylene (1135-32-6) → ([Cu2(3,3',4,4'-diphenylsulfonetetracarboxylic acid-4H)(1,2-bis(4-pyridyl)ethene)(H2O)2]*4H2O)n

Conditions	Yield
With NaOH In water High Pressure; mixt. of Cu(NO3)2*3H2O (0.10 mmol), 3,3',4,4'-diphenylsulfonetetracarboxylic dianhydride (0.05 mmol), 1,2-bis(4-pyridyl)ethene (0.05 mmol), NaOH(0.2 mmol) and H2O stirred (20 min) in air; heated in autoclave (160.de gree.C, 72 h); cooled to room temp. (5°C/h); elem. anal.;	36%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + Pyridine-2,3-dicarboxylic acid (89-00-9) + ammonium chloride (12125-02-9) + cobalt(II) chloride (7646-79-9) → C58H24Co2N22O2S

Conditions	Yield
With ammonium dimolybdate; urea for 10h; Heating; Reflux;	25%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + Pyridine-2,3-dicarboxylic acid (89-00-9) + ammonium chloride (12125-02-9) + manganese(ll) chloride → C58H24Mn2N22O2S

Conditions	Yield
With ammonium dimolybdate; urea for 10h; Heating; Reflux;	25%

N,N'-dipiperidylpropane (31951-46-9) + 3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + water (7732-18-5) + zinc(II) acetate dihydrate (5970-45-6) → [H2(1,3-bis(piperidyl)propane)]2[Zn2(4,4′-sulfonediphthalate)2]*H2O

Conditions	Yield
With triethylamine In methanol at 140℃; for 72h; pH=7; High pressure;	20%

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride (2540-99-0) + Pyridine-2,3-dicarboxylic acid (89-00-9) + ammonium chloride (12125-02-9) + zinc(II) chloride (7646-85-7) → C58H24N22O2SZn2

Conditions	Yield
With ammonium dimolybdate; urea for 10h; Heating; Reflux;	11%

Upstream product

• 25884-43-9 3,3′,4,4′-diphenylsulfidetetracarboxylic dianhydride 
• 10595-31-0 3,3’,4,4’-diphenylsulfonetetracarboxylic acid 

Downstream Products

• 10595-31-0 3,3’,4,4’-diphenylsulfonetetracarboxylic acid 

Relevant articles and documents

A 3, 3 ', 4, 4' - diphenyl sulphone four carboxylic anhydride method (by machine translation)

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