25543-63-9Relevant academic research and scientific papers
N-Trialkylsilylimines as Coupling Partners for Pd-Catalyzed C-N Bond-Forming Reactions: One-Step Synthesis of Imines and Azadienes from Aryl and Alkenyl Bromides
Barluenga, Jose,Aznar, Fernando,Valdes, Carlos
, p. 343 - 345 (2007/10/03)
A good substitute: Imines, 1-azadienes, 2-azadienes, and even 2-azatrienes are prepared in one step from aryl and alkenyl bromides by palladium-catalyzed cross-coupling with N-trimethylsilylimines. The reaction introduces N-trimethylsilylimines as a synthetic equivalent for the R-CH=N moiety in C-N bond-forming reactions.
