4-[(4-METHOXYBENZYLIDENE)AMINO]BIPHENYL

Base Information

Chemical Name:4-[(4-METHOXYBENZYLIDENE)AMINO]BIPHENYL
CAS No.:25543-63-9
Molecular Formula:C20H17 N O
Molecular Weight:287.361
Hs Code.:2922299090
Mol file:25543-63-9.mol

Synonyms:4-Biphenylamine,N-(p-methoxybenzylidene)- (6CI,8CI); p-Anisylidene-p'-biphenylamine

Suppliers and Price of 4-[(4-METHOXYBENZYLIDENE)AMINO]BIPHENYL

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
N-[(E)-(4-METHOXYPHENYL)METHYLIDENE][1,1'-BIPHENYL]-4-AMINE AldrichCPR
250mg
$ 112.00

Total 4 raw suppliers

Chemical Property of 4-[(4-METHOXYBENZYLIDENE)AMINO]BIPHENYL

Chemical Property:

Vapor Pressure:3.59E-08mmHg at 25°C
Melting Point:163-164 °C
Boiling Point:459°C at 760 mmHg
PKA:3.85±0.50(Predicted)
Flash Point:185.8°C
PSA：21.59000
Density:1.02g/cm³
LogP:5.11280

Purity/Quality:

95% ^*data from raw suppliers

N-[(E)-(4-METHOXYPHENYL)METHYLIDENE][1,1'-BIPHENYL]-4-AMINE AldrichCPR ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 4-[(4-METHOXYBENZYLIDENE)AMINO]BIPHENYL

There total 2 articles about 4-[(4-METHOXYBENZYLIDENE)AMINO]BIPHENYL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 92-66-0
4-bromo-1,1'-biphenyl

: 64187-51-5
N-trimethylsilyl(4-methoxy)benzaldimine

: 92-52-4,1594-86-1
biphenyl

: 25543-63-9
N-(3-methoxybenzylidene)-[1,1'-biphenyl]-4-amine

: 874-90-8
4-methoxybenzonitrile

Guidance literature:: With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In toluene; at 90 ℃; for 2h;
DOI:10.1002/anie.200352808

Reference yield:

: 92-67-1
4-phenylalanine

: 123-11-5
4-methoxy-benzaldehyde

: 25543-63-9
N-(3-methoxybenzylidene)-[1,1'-biphenyl]-4-amine

Guidance literature:: With ethanol;

Reference yield: 77.0%

: 25543-63-9
N-(3-methoxybenzylidene)-[1,1'-biphenyl]-4-amine

: 75-03-6
ethyl iodide

: 1169936-51-9
C₂₂H₂₃NO

Guidance literature:: With triethyl borane; tris-(trimethylsilyl)silane; 1,1,1-trifluoro-N-(4-oxido-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)methanesulfonamide; oxygen; In tetrahydrofuran; at -40 ℃; for 24h; optical yield given as %ee; enantioselective reaction;
DOI:10.1016/j.tetlet.2009.02.136