2559-41-3Relevant articles and documents
Rhodium(II)-catalyzed addition of 2-diazo(fluoroalkyl)acetoacetates to sulfides: A simple synthesis of stable sulfonium ylides
Zhu, Shizheng,Zhu, Shifa,Liao, Yuanxi
, p. 1071 - 1076 (2004)
2-Diazo(fluoroalkyl)acetoacetates 1 reacted readily with many sulfides under mild reaction conditions in the presence of catalytic Rh2(OAc)4 affording to the corresponding sulfonium ylides. While thianthrene gave trans-thianthrenium