256464-90-1Relevant articles and documents
Enantioselective total synthesis of bistramide A
Crimmins, Michael T.,DeBaillie, Amy C.
, p. 4936 - 4937 (2007/10/03)
The enantioselective synthesis of bistramide A has been achieved with a longest linear sequence of 18 steps. The synthetic strategy involves the use of a distereoselective glycolate alkylation, an aldol addition of a chlorotitanium enolate of N-acylthiazolidinthione, and a Sharpless asymmetric epoxidation to synthesize the three key fragments. Copyright
Toward creation of a universal NMR database for the stereochemical assignment of acyclic compounds: Proof of concept
Lee, Jinhwa,Kobayashi, Yoshihisa,Tezuka, Kenichi,Kishi, Yoshito
, p. 2181 - 2184 (2008/02/09)
Oasomycin B: R = α-D-mannosyl Using the C.5-C.10 portion of the oasomycin class of natural products, the reliability and usefulness of an NMR database for the stereochemical assignment of acyclic compounds has been demonstrated. The predicted relative stereochemistry based on the NMR database has unambiguously been established via synthesis.