257610-57-4Relevant academic research and scientific papers
Fluoride ion-initiated α-fluorovinylation of carbonyl compounds with α-fluorovinyldiphenylmethylsilane
Hanamoto, Takeshi,Harada, Shigeo,Shindo, Keiko,Kondo, Michio
, p. 2397 - 2398 (2007/10/03)
α-Fluorovinyldiphenylmethylsilane was synthesized in one step from 1,1- difluoroethylene; the TBAF-initiated reaction of the silane with carbonyl compounds smoothly proceeded to give the corresponding α-fluoroallylic alcohols in good yields.
An application of the trost reaction to the stereoselective synthesis of trans-tetrasubstituted fluoroalkenes
Fish, Paul V.,Pulla Reddy,Lee, Cheol H.,Johnson, William S.
, p. 8001 - 8004 (2007/10/02)
The coupling of β-fluoroallylic acetates (1) with stabilised ester-enolates (3), in the presence of catalytic palladium(0), gave tetrasubstituted fluoroalkenes (2) in good yield and with generally satisfactory trans-stereoselectivity.
