257882-74-9

Upstream product

• 101640-53-3 4-Methoxy-benzoic acid bicyclo[4.2.0]octa-1,3,5-trien-7-yl ester 
• 214550-36-4 (+/-)-3-(4'-methoxyphenyl)isochroman 
• 5097-25-6 N-(4-methoxylphenyl)piperidine 
• 176910-67-1 2-(4-methoxyphenylethynyl)benzaldehyde 
• 88154-24-9 N-(3-chlorophenyl)tetrahydropyrrole 
• 768-60-5 4-methoxyphenylacetylen 
• 34824-58-3 2-(2-bromophenyl)-1,3-dioxolan 
• 6630-33-7 ortho-bromobenzaldehyde 

Downstream Products

• 20435-81-8 3-(4-methoxyphenyl)isoquinoline 
• 1132675-32-1 diethyl 3-(4-methoxyphenyl)-2-p-tolyl-1,2-dihydroisoquinolin-1-ylphosphonate 
• 1132675-30-9 diethyl 3-(4-methoxyphenyl)-2-phenyl-1,2-dihydroisoquinolin-1-ylphosphonate 
• 1132675-35-4 diethyl 2-(4-fluorophenyl)-3-(4-methoxyphenyl)-1,2-dihydroisoquinolin-1-ylphosphonate 

Relevant academic research and scientific papers

Solvent-regulated coupling of 2-alkynylbenzaldehydes with cyclic amines: Selective synthesis of fused N-heterocycles and functionalized naphthalene derivatives

An efficient synthesis of 1,2,3,4-tetrahydrobenzo[g]-quinoline derivatives through PdCl2-catalyzed, TBHP-promoted, and toluene-mediated dehydrogenation/[4+2] cycloaddition of saturated cyclic amines with 2-alkynylbenzaldehydes was developed. On the contrary, when the reaction medium was changed from toluene to DMSO/H2O, another class of important compounds, naphthyl chain amines, formed via a dehydrogenation?intermolecular condensation? C?N bond cleavage?intramolecular condensation pathway, was obtained with good selectivity.

An efficient route to polysubstituted tetrahydronaphthols: Silver-catalyzed [4+2] cyclization of 2-alkylbenzaldehydes and alkenes

Silver bullet: A methodology for stereoselective synthesis of polysubstituted tetrahydronaphthols catalyzed by [Ag+]/NPO has been developed. The reactions proceeded through an unprecedented [4+2] cyclization of 2-(2-formylphenyl)ethanone and an alkene, in both inter- and intramolecular fashion. NPO=pyridine N-oxide. Copyright

Oxidation of 3-arylisochromans by dimethyldioxirane. An easy route to substituted 3-arylisocoumarins

The selective oxidation of the two different benzylethereal position of 3-arylisochromans by dimethyldioxirane as a function of different substituents on the aromatic rings was studied. The easy oxidation of these compounds was exploited for a new easy ac

THERMOLYTIC RING OPENING OF ACYLOXYBENZOCYCLOBUTENES: AN EFFICIENT ROUTE TO 3-SUBSTITUTED ISOQUINOLINES

Upon flash vacuum pyrolysis acyloxybenzocyclobutenes 4 rearrange through an intramolecular 1,5-acyl shift to 2-formylbenzyl ketones 6 which can be converted to 3-substituted isoquinolines 7.