25856-06-8

Basic information

• Product Name: 1-Propanone, 2,3-dibromo-1-(4-chlorophenyl)-3-phenyl-
• CAS NO: 25856-06-8
• Molecular Formula: C15H11Br2ClO
• Molecular Weight: 402.513
• Mol File: 25856-06-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 2,3-dibromo-1-(4-chlorophenyl)-3-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 2,3-dibromo-1-(4-chlorophenyl)-3-phenyl-(25856-06-8)
• EPA Substance Registry System: 1-Propanone, 2,3-dibromo-1-(4-chlorophenyl)-3-phenyl-(25856-06-8)

Safety Data

• Hazardous Substances Data: 25856-06-8(Hazardous Substances Data)

Upstream product

• 956-02-5 4'-chlorochalcone 
• 99-91-2 para-chloroacetophenone 
• 100-52-7 benzaldehyde 
• 22966-22-9 (E)-1-(4-chlorophenyl)-3-phenyl-2-propen-1-one 

Downstream Products

• 22966-22-9 (E)-1-(4-chlorophenyl)-3-phenyl-2-propen-1-one 
• 911678-05-2 1-(4-(4-chlorophenyl)-6-phenylpyrimidin-2-yl)hydrazine-1-carbonitrile 
• 100272-18-2 (4-chlorophenyl)(4,5-diphenyl-1H-pyrazol-3-yl)methanone 
• 50603-94-6 (Z)-2-bromo-1-(4-chlorophenyl)-3-phenylprop-2-en-1-one 
• 84374-75-4 4-(4-Chloro-phenyl)-6-phenyl-1,6-dihydro-pyrimidine-2,5-dithione 
• 84374-81-2 4-(4-Chloro-phenyl)-6-phenyl-1,6-dihydro-pyrimidine-2,5-dione 
• 74990-14-0 3-(4-Chloro-phenyl)-1-(2,4-dinitro-phenyl)-5-phenyl-1,5-dihydro-pyrazole-4-thione 
• 75008-93-4 3-(4-Chloro-phenyl)-1-(2,4-dinitro-phenyl)-5-phenyl-1,5-dihydro-pyrazol-4-one 
• 74990-18-4 3-(4-Chloro-phenyl)-1,5-diphenyl-1,5-dihydro-pyrazole-4-thione 
• 74990-07-1 3-(4-Chloro-phenyl)-1,5-diphenyl-1,5-dihydro-pyrazol-4-one 

Relevant articles and documents

Modular access to 1,2-allenyl ketones based on a photoredox-catalysed radical-polar crossover process

Herein, a new protocol dealing with the preparation of 1,2-allenyl ketones has been successfully developedviathe reactions of enynes with radicals enabled by dual photoredox/copper catalysis. Based on the results of a deuteration experiment and the competition reaction between cyclopropanation and allenation, the mechanism based on a photoredox-neutral-catalysed radical-polar crossover process has been proposed. Synthetic applications of allenes have also been demonstrated.

Visible-light photoredox catalysis enabled bromination of phenols and alkenes

A mild and efficient methodology for the bromination of phenols and alkenes has been developed utilizing visible light-induced photoredox catalysis. The bromine was generated in situ from the oxidation of Br- by Ru(bpy)33+, both of which resulted from the oxidative quenching process.

Chemoselective C-C bond cleavage of epoxide motifs: Gold(I)-catalyzed diastereoselective [4+3] cycloadditions of 1-(1-Alkynyl)oxiranyl ketones and nitrones

Cutting carbon! A novel facile strategy for the C-C bond cleavage of oxiranyl ketones has been developed. Carbophilic gold(I) activation of the alkyne side chain mediates a heterocyclization and subsequent C-C bond cleavage (see scheme).