259198-96-4

Basic information

• Product Name: (3R)-4-(4-methoxybenzyloxy)-3-methylbutyrnitrile
• Synonyms: (3R)-4-(4-methoxybenzyloxy)-3-methylbutyrnitrile
• CAS NO: 259198-96-4
• Molecular Weight: 219.283
• Mol File: 259198-96-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (3R)-4-(4-methoxybenzyloxy)-3-methylbutyrnitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (3R)-4-(4-methoxybenzyloxy)-3-methylbutyrnitrile(259198-96-4)
• EPA Substance Registry System: (3R)-4-(4-methoxybenzyloxy)-3-methylbutyrnitrile(259198-96-4)

Safety Data

• Hazardous Substances Data: 259198-96-4(Hazardous Substances Data)

Upstream product

• 136320-65-5 1-((S)-3-iodo-2-methylpropoxymethyl)-4-methoxybenzene 
• 136320-64-4 (2R)-3-[(4-methoxybenzyl)oxy]-2-methylpropanol 
• 143-33-9 sodium cyanide 
• 527743-00-6 4-methyl-benzenesulfonic acid (S)-3-(4-methoxy-benzyloxy)-2-methyl-propyl ester 

Downstream Products

• 259199-04-7 tert-Butyl-((Z)-4-{(2R,6S)-6-[(R)-3-(4-methoxy-benzyloxy)-2-methyl-propyl]-5,6-dihydro-2H-pyran-2-yl}-but-2-enyloxy)-dimethyl-silane 
• 259199-02-5 (Z)-4-{(2R,6S)-6-[(R)-3-(4-Methoxy-benzyloxy)-2-methyl-propyl]-5,6-dihydro-2H-pyran-2-yl}-but-2-enoic acid methyl ester 
• 259199-03-6 (Z)-4-{(2R,6S)-6-[(R)-3-(4-Methoxy-benzyloxy)-2-methyl-propyl]-5,6-dihydro-2H-pyran-2-yl}-but-2-en-1-ol 
• 259198-99-7 (4S,6R)-4-(1-ethoxyallyloxy)-7-(p-methoxybenzyloxy)-6-methylhept-1-ene 
• 259199-01-4 {(2R)-6-[3-(4-methoxybenzyloxy)-2-methyl-propyl]-(2R,6S)-5,6-dihydro-2H-pyran-2-yl}acetaldehyde 
• 259199-00-3 (2S,6RS)-7-ethoxy-2-[(2R)-3-(4-methoxybenzyloxy)-2-methylpropyl]-3,6-dihydro-2H-pyran 
• 259198-98-6 (4S,6R)-7-(p-methoxybenzyloxy)-6-methylhept-1-en-4-ol 
• 115268-43-4 laulimalide 
• 445306-64-9 4-[1-[2-(3-{6-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-2-methyl-propyl)-allyl]-5-(tert-butyl-diphenyl-silanyloxy)-6-methoxymethoxy-8-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-octa-2,7-dienyloxy]-pentan-2-one 
• 445306-63-8 4-[1-[2-(3-{6-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-2-methyl-propyl)-allyl]-5-(tert-butyl-diphenyl-silanyloxy)-6-methoxymethoxy-8-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-octa-2,7-dienyloxy]-pentan-2-ol 
• 445306-66-1 C₅₄H₈₄O₈Si₂ 
• 445306-65-0 2-(3-{6-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-2-methyl-propyl)-8-(tert-butyl-diphenyl-silanyloxy)-9-methoxymethoxy-11-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-undeca-1,5,10-trien-4-ol 
• 527743-03-9 toluene-4-sulfonic acid 3-{6-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-2-methyl-propyl ester 
• 445306-73-0 (2R,6S)-tert-butyl-(2-{6-[(2R)-3-(4-methoxybenzyloxy)-2-methylpropyl]-5,6-dihydro-2H-pyran-2-yl}-ethoxy)-dimethylsilane 

Relevant articles and documents

A novel approach to the CDE ring system of pectenotoxin-4 triggered by VO(acac)2-induced epoxy-acetalization

(Chemical Equation Presented) A novel approach to the CDE fragment of pectenotoxin-4 is described wherein the bicyclic acetal is constructed via a cascade cyclization induced by VO(acac)2 epoxidation of a homoallylic alcohol.

Synthesis of the C1-C12-dihydropyran segment of the antitumor agent laulimalide by ring closing metathesis

A stereocontrolled synthesis of the C1-C12 fragment 3 of laulimalide utilizing a ring closing metathesis with Grubbs' catalyst as the key step is described.