25982-72-3

Basic information

• Product Name: 2-methyl-3-phenyl-but-3-en-2-ol
• Synonyms: 2-methyl-3-phenyl-but-3-en-2-ol
• CAS NO: 25982-72-3
• Molecular Weight: 162.232
• Mol File: 25982-72-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 2-methyl-3-phenyl-but-3-en-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-3-phenyl-but-3-en-2-ol(25982-72-3)
• EPA Substance Registry System: 2-methyl-3-phenyl-but-3-en-2-ol(25982-72-3)

Safety Data

• Hazardous Substances Data: 25982-72-3(Hazardous Substances Data)

Upstream product

• 769-57-3 α,β,β-trimethylstyrene 
• 16812-43-4 bis(trimethylstannyl)methane 
• 7473-99-6 α-chloroisobutyrophenone 
• 536-74-3 phenylacetylene 
• 98-86-2 acetophenone 
• 67-64-1 acetone 
• 10152-58-6 2,2-dimethyl-3-phenyloxirane 
• 75-05-8 acetonitrile 
• 563-80-4 3-methyl-butan-2-one 
• 13686-41-4 2,2-dimethyl-3-phenyl-3-butenoic acid 
• 108-86-1 bromobenzene 
• 115-19-5 2-methyl-but-3-yn-2-ol 
• 98-81-7 1-bromovinylbenzene 
• 21578-99-4 rac-α,β,β-trimethylstyrene oxide 

Downstream Products

• 108475-84-9 (+/-)-4-methyl-5-phenyl-cyclohex-4-ene-1r,2c-dicarboxylic acid-anhydride 
• 1263406-31-0 2-(1-hydroxyl-(1-methyl)ethyl)-2-phenyloxirane 
• 79963-03-4 4-methyl-5-oxo-4-phenyl-hexanenitrile 
• 34672-84-9 1-methoxy-2,2,6,6-tetramethylpiperidine 
• 102261-91-6 2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)acetonitrile 
• 869811-12-1 methyl 5-methyl-4-phenylhex-4-enoate 

Relevant articles and documents

Selective Aerobic Oxygenation of Tertiary Allylic Alcohols with Molecular Oxygen

Aerobic epoxidation of tertiary allylic alcohols remains a significant challenge. Reported here is an efficient and highly chemoselective copper-catalyzed epoxidation and semipinacol rearrangement reaction of tertiary allylic alcohols with molecular oxygen. The solvent 1,4-dioxane activates dioxygen, thereby precluding the addition of a sacrificial reductant.

N-BuLi/LiCH2CN-mediated one-carbon homologation of aryl epoxides into conjugated allyl alcohols

A series of styrene oxides in the presence of a 1:1 mixture of n-butyllithium (n-BuLi) and lithioacetonitrile (LiCH2CN) in THF are converted into one-carbon homologated allyl alcohols in an unusual regioselective manner.

A novel palladium-catalyzed asymmetric cyclocarbonylation of allylic alcohols to γ-butyrolactones

A catalyst system based on [Pd2(dba)3]·CHCl3/(-)-BPPM has been found to effect asymmetric cyclocarbonylation of certain prochiral allylic alcohols to produce good yields of optically enriched γ-butyrolactones. The reaction