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2613-13-0

Benzaldehyde-N(4),N(4)-dimethylthiosemicarbazone is a chemical compound with the molecular formula C10H14N4S. It is a derivative of benzaldehyde, where the aldehyde group is replaced by a thiosemicarbazone moiety. benzaldehyde-N(4),N(4)-dimethylthiosemicarbazone is known for its potential applications in analytical chemistry, particularly as a reagent for the detection and determination of metal ions. It forms colored complexes with certain metals, which can be used for their identification and quantification. The compound is also of interest in the field of coordination chemistry due to its ability to act as a ligand in the formation of coordination complexes. Its structure and reactivity make it a subject of study in organic synthesis and potentially in the development of new materials and pharmaceuticals.

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  • 2613-13-0 Structure

  • Basic information

    1. Product Name: benzaldehyde-N(4),N(4)-dimethylthiosemicarbazone
    2. Synonyms: benzaldehyde-N(4),N(4)-dimethylthiosemicarbazone
    3. CAS NO:2613-13-0
    4. Molecular Formula:
    5. Molecular Weight: 207.299
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 2613-13-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: benzaldehyde-N(4),N(4)-dimethylthiosemicarbazone(CAS DataBase Reference)
    10. NIST Chemistry Reference: benzaldehyde-N(4),N(4)-dimethylthiosemicarbazone(2613-13-0)
    11. EPA Substance Registry System: benzaldehyde-N(4),N(4)-dimethylthiosemicarbazone(2613-13-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 2613-13-0(Hazardous Substances Data)

2613-13-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 2613-13-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,6,1 and 3 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 2613-13:
(6*2)+(5*6)+(4*1)+(3*3)+(2*1)+(1*3)=60
60 % 10 = 0
So 2613-13-0 is a valid CAS Registry Number.

2613-13-0Relevant articles and documents

Reaction of schiff base of thiohydrazides with P(NR2)3

Huang, Tian-Bao,Liu, Ling-Fei,Yu, Xiao-Ming,Yang, Wen-Qian,Qian, Xu-Hong,Zhang, Jing-Ling

, p. 307 - 312 (1997)

Three pathways were observed in the reactions of Schiff bases of Thiohydrazides with P(NR2)3,. (a) MeS-R2N exchange: MeS-C(=S)-NHN=CHPh (1) reacted with P(NR2)3 led to new Schiff bases, R2N-C(=S)-NHN=CH=Ph (2). (b) Cleavage of C=S bond and the formation of P=S bond: H2N-C(=S)-NHN=CH=Ph (3) reacted with P(NR2)3 gave rise to the thiophosphoric amide, (Et2N)2P(=S)-NH-CH=N-N=CH-Ph (4). (c) Formation of thiadiazole and triazole: Schiff bases 2a and H2N(MeS)C=N-N=CH-Ph (6) reacted with P(NR2)3 respectively and produced 5-dimethylamino-2-phenyl-2,3-(2H)-1,3,4-thiadiazole (5) and 5-methylthio-2-phenyl-2,3-(2H)-1,3,4-triazole (7).

Thiosemicarbazone Complexes of Uranium(IV)

Gr?dler, Dennis,Haseloer, Alexander,Tobeck, Christian,Bulut, Yusuf,Neud?rfl, J?rg M.,Mathur, Sanjay,Ruschewitz, Uwe,Klein, Axel,Wickleder, Mathias S.,Zegke, Markus

supporting information, p. 1137 - 1139 (2021/02/26)

The first homoleptic thiosemicarbazone complexes of uranium were isolated by reacting uranium tetrachloride in a salt metathesis or acid-base reaction with four equivalents of Na(BzTSC) or H(BzTSC) (BzTSC=benzylthiosemicarbazone), carrying a non-methylated (L1), monomethylated (L2) or dimethylated (L3) terminal amino group, in moderate yields. [U(BzTSCNH2)4] (1), [U(BzTSCNH(CH3))4] (2) and [U(BzTSCN(CH3)2)4] (3) show a remarkable stability towards air, with oxidation potentials in THF between +0.43 and +0.53 V and reduction potentials between ?2.53 and ?2.67 V vs. ferrocene/ferrocenium. The simple methylation of the terminal amino group of the ligand allows for controlled changes in the coordination environments of the complexes. Thermogravimetric analyses indicate that the complexes are stable up to 155 °C.

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