26226-58-4 Usage
General Description
(2E)-2-(hydroxyimino)-1-phenylpropan-1-ol is a chemical compound with the molecular formula C9H11NO2. It is an organic compound that belongs to the class of alcohols and oximes. (2E)-2-(hydroxyimino)-1-phenylpropan-1-ol is a pale yellow oil that is insoluble in water but soluble in organic solvents. It is commonly used in organic synthesis and as a reagent in chemical reactions due to its ability to undergo various transformations. It is also known for its use in the preparation of pharmaceuticals and agrochemicals. The compound has potential applications in the field of medicinal chemistry and drug development.
Check Digit Verification of cas no
The CAS Registry Mumber 26226-58-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,6,2,2 and 6 respectively; the second part has 2 digits, 5 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 26226-58:
(7*2)+(6*6)+(5*2)+(4*2)+(3*6)+(2*5)+(1*8)=104
104 % 10 = 4
So 26226-58-4 is a valid CAS Registry Number.
26226-58-4Relevant articles and documents
Kinetics and Mechanism of the Alkaline Release of Phenyl(mercapto)tetrazoles from α-Oximes
Boggs, Roger A.,Hasan, Fariza B.,Mahoney, J. Barry,Mehta, Avi C.,Palumbo, Catherine M. K.,et al.
, p. 1271 - 1277 (2007/10/02)
Compounds such as α-phenyl(mercapto)tetrazole (PMT) oxime (9) undergo rapid elimination of the PMT anion in base via a nitrosoene intermediate.Solution kinetics and HPLC analysis of reaction products are consistent with the mechanism shown in Scheme 2.For open chain oximes such as 4, substitution α to the oxime increases the rate of release of PMT and is attributed to the relief of strain when a crowded reactant is converted to a less-crowded product.For cyclic oximes, the six-membered ring compounds are more reactive than the corresponding five-membered compounds.A linear isokinetic relationship between the entropy and enthalpy of activation was found with β = 346 +/- 51 K.Entropies of activation were found to range from -7 to +24 c.u. (1 c.u. = 4.184 J mol-1 K-1) and support the proposed mechanism.