26306-00-3

Basic information

• Product Name: [(6-Bromohexyl)oxy]trimethylsilane
• Synonyms: [(6-Bromohexyl)oxy]trimethylsilane
• CAS NO: 26306-00-3
• Molecular Formula: C₉H₂₁BrOSi
• Molecular Weight: 253.25
• Mol File: 26306-00-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 80-84 °C(Press: 2 Torr)
• Appearance: /
• Density: 1.089±0.06 g/cm3(Predicted)
• CAS DataBase Reference: [(6-Bromohexyl)oxy]trimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: [(6-Bromohexyl)oxy]trimethylsilane(26306-00-3)
• EPA Substance Registry System: [(6-Bromohexyl)oxy]trimethylsilane(26306-00-3)

Safety Data

• Hazardous Substances Data: 26306-00-3(Hazardous Substances Data)

Usage

General Description

[(6-Bromohexyl)oxy]trimethylsilane, also known as 3-bromo-1-hexanol trimethylsilyl ether, is an organosilicon compound with the chemical formula C9H21BrOSi. It is a clear, colorless liquid that is commonly used as a reagent in organic synthesis and as a protecting group for alcohols. [(6-Bromohexyl)oxy]trimethylsilane is often employed in the construction of functionalized siloxane-based materials and in the synthesis of bioactive molecules. It is an important building block in the production of pharmaceuticals, agrochemicals, and other specialty chemicals. Additionally, [(6-Bromohexyl)oxy]trimethylsilane is soluble in a wide range of organic solvents and can undergo various organic transformations, making it a versatile and valuable tool in organic chemistry research and industrial applications.

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 4286-55-9 1-bromo-6-hexanol 
• 4224-70-8 6-bromohexanoic acid 
• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 

Downstream Products

• 114423-59-5 3-<6'-(trimethylsilyloxy)hexyl>-1-<(trimethylsilyl)oxy>cyclohexene 
• 35148-19-7 (E)-9-dodecenyl acetate 
• 58223-46-4 7-methylnonanal 
• 33956-49-9 (8E,10E)-dodeca-8,10-dienol 
• 114423-60-8 trans,trans-3-(6-hydroxyhexyl)-1,2-cyclohexanediol 
• 114423-61-9 trans,trans-3-(6'-bromohexyl)-1,2-cyclohexanediol 
• 114423-62-0 trans,trans-3-(6'-bromohexyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane 
• 114423-65-3 trans,trans-3-(10'-hydroxy-6'-decenyl)-1,2-biscyclohexane 
• 114423-66-4 trans,trans-3-(10'-oxo-6'-decenyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane 
• 114423-64-2 trans,trans-3-(10'-acetoxy-6'-decenyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane 
• 114528-96-0 trans,trans-(5S)-5-<9'-(2,3-bis((dimethylthexylsilyl)oxy)cyclohexyl)-3'-nonenyl>-2,3-dihydrofuranone 
• 114423-63-1 <6'-(trans,trans-1'',2''-bis((dimethylthexylsilyl)oxy)-3''-cyclohexyl)hexyl>triphenylphosphonium bromide 
• 114423-68-6 trans,trans-5-<9'-(2'',3''-dihydroxycyclohexyl)-3'-nonenyl>-3-methylenetetrahydro-2-furanone 
• 114489-16-6 trans,trans-(5S)-5-<9'-(2,3-dihydroxycyclohexyl)-3'-nonenyl>-3-methylenetetrahydro-2-furanone 

Relevant articles and documents

Exo and endohormones. XX. Synthesis of racemic 2-ethyl-1,6-dioxaspiro[4,4]nonane, the aggregation pheromone of pityogenes chalcographus (Coleoptera, Scolytidae)

The synthesis of a diastereoisomeric mixture of 2-etyl-1,6-dioxaspiro[4,4]nonane (chalcograne) a main component of the aggregation pheromone of the spruce bark beetle Pityogenes chalcographus (Coleoptera, Scolytidae), a serious pest in European forests, by 1,7-nonanediol cyclization using Pb(OAc)4 is given below. The side products of spirocyclization were identified by GC/MS.

Synthesis of codling moth attractant

Sterospecific synthesis of an attractant for the codling moth by reacting sorbic aldehyde with an organo-metallic reagent to yield a 1-ether of trans-8-trans-10-dodecadiene-1,7-diol which is reduced via a 7-sulfonic acid ester to yield an ether of trans-8-trans-10-dodecadiene-1-ol and hydrolyzed to trans-8-trans-10-dodecadien-1-ol. SPC1