2650-53-5Relevant articles and documents
Nanoparticles with Near-Infrared Emission Enhanced by Pillararene-Based Molecular Recognition in Water
Shi, Bingbing,Jie, Kecheng,Zhou, Yujuan,Zhou, Jiong,Xia, Danyu,Huang, Feihe
, p. 80 - 83 (2016)
Here we report the unprecedented preparation of nanoparticles with near-infrared (NIR) emission enhanced by host-guest complexation between a water-soluble pillar[5]arene (WP5) and a cyanostilbene derivative (1) in water. Amphiphilic 1 self-assembles in water to form nanoribbons with relatively weak NIR emission at low concentrations. However, after addition of equimolar WP5, these nanoribbons transform into nanoparticles with stronger NIR emission due to the formation of a supramolecular amphiphile and host-guest complexation-enhanced aggregation. These nanoparticles show pH responsiveness, and collapse after treatment with acid. More importantly, these nanoparticles can be used in living cell imaging.
USE OF QUATERNARY AMMONIUM COMPOUNDS AS SPECIFIC BLOCKERS OF TRANSPORT THROUGH AQUAPORIN, COMPOSITIONS COMPRISING THE COMPOUNDS AND METHOD OF SELECTING THE COMPOUNDS
-
Page/Page column 17-18, (2008/06/13)
The present invention relates to the use of quaternary ammonium compounds for the preparation of a composition for specifically blocking transport through a particular type of aquaporin. The invention further relates to compositions comprising such quaternary ammonium compounds for use in various applications.
Photoprocesses on Colloidal Clay Systems. 2. Quenching Studies and the Effect of Surfactants on the Luminescent Properties of Pyrene and Pyrene Derivatives Adsorbed on Clay Colloids
DellaGuardia, R. A.,Thomas, J. K.
, p. 3550 - 3557 (2007/10/02)
The cationic fluorescent probe trimethylammonium bromide (PN+) is adsorbed by the colloidal particles of the clay minerals montmorillonite and kaolin.The emission spectrum, polarization of fluorescence measurements, and transient fluorescence decay characteristics of PN+ are used to study the nature of its adsorbed state.Quaternary ammonium surfactants of varying hydrocarbon chain length cause a rearrangement of the PN+ molecules on the surface and decrease its interaction with the mineral surface.Quenching studies with nonionic andcationic molecules indicate that diffusion on the surface of montmorillonite is reduced below that observed in aqueous solution while the apparent rates obtained with kaolin particles are increased.Montmorillonite particles with a surfactant bilayer surrounding their surfaces are formed by the addition of an excess amount of surfactant to the colloid.The emission spectrum and the steady-state quenching studies yield information on the location of pyrene on these particles, as well as on the nature of the colloidal particles.